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 Vol . 2, 2002 Supplement
Grubbs' Catalysts & MacMillan's OrganoCatalysts™
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Grubbs' Catalysts / MacMillan's OrganoCatalysts™
Verkade's Superbases / Metal Catalysts and Ligands / References
Metal Catalysts and Ligands for Organic Synthesis
| Chromium |
53,194-4  |
(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-
cyclohexanediaminochromium (III) chloride |
1g; 5g |
| 53,195-2 |
(S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-
cyclohexanediaminochromium (III) chloride |
1g; 5g |
| Cobalt |
| 47,459-2 |
(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-
1,2-cyclohexanediaminocobalt (II) |
1g; 5g; 25g |
| 47,460-6 |
(S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-
1,2-cyclohexanediaminocobalt (II) |
1g; 5g; 25g |
| 24,525-9 |
Dicarbonylcyclopentadienylcobalt,tech. |
5g; 25g |
| Copper |
| 28,367-3 |
Copper(II) trifluoromethanesulfonate,98% |
5g; 25g |
| 34,627-6 |
Tetrakis(acetonitrile)copper(I)
hexafluorophosphate |
5g; 25g |
| Iridium |
| 27,513-1 |
Chloro(1,5-cyclooctadiene)iridium(I) dimer, 97% |
100mg; 500mg |
| 33,749-8 |
(1,5-Cyclooctadiene)(pyridine)
(tricyclohexylphosphine) iridium(I) PF6
(Crabtree's Catalyst) |
50mg; 250mg |
| Iron |
| 17,726-1 |
1,1'-Bis(diphenylphosphino)ferrocene, 97% |
1g; 10g |
| Manganese |
| 40,444-6 |
(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-
1,2-cyclohexanediaminomanganese(III)
chloride, 98% [(R,R)-Jacobsen’s Catalyst] |
1g; 5g; 25g |
| 40,445-4 |
(S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-
1,2-cyclohexanediaminomanganese(III)
chloride, 98% [(S,S)-Jacobsen’s Catalyst] |
1g; 5g; 25g |
| Nickel |
| 24,498-8 |
Bis(1,5-cyclooctadiene)nickel(0) |
2g |
| 47,055-4 |
[1,1'-Bis(diphenylphosphino)ferrocene]
dichloronickel(II), 97% |
1g |
| 56,767-1 |
Dichlorobis(trimethylphosphine)
nickel(II), 97% |
1g; 5g |
| 23,711-6 |
Dichlorobis(triphenylphosphine)
nickel(II), 98% |
10g; 50g; 500g |
| Nitrogen |
| 40,441-1 |
(R,R)-(-)-N,N'-Bis(di-tert- butylsalicylidene)-1,2-
cyclohexanediamine, 98% |
1g; 5g |
| 40,443-8 |
(S,S)-(+)-N,N'-Bis(di-tert-butylsalicylidene)-1,2-
cyclohexanediamine, 98% |
1g; 5g |
| 49,606-5 |
[R-(R*,R*)]-2,6-Bis(4,5-dihydro-4-phenyl-2-
oxazolyl)pyridine, 98% |
500mg; 2g |
| 49,607-3 |
[S-(R*,R*)]-2,6-Bis(4,5-dihydro-4-phenyl-2-
oxazolyl)pyridine, 98% |
500mg; 2g |
| 57,407-4 |
1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride |
500mg; 2g |
| 57,406-6 |
1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride |
1g; 5g |
| Oxygen |
| 46,486-4 |
rac-6,6'-Dibromo-1,1'-bi-2-naphthol, 97% |
1g; 5g |
| 48,261-7 |
(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol, 98% |
500mg |
| 48,262-5 |
(S)-(+)-6,6'-Dibromo-1,1'-bi-2-naphthol, 97% |
500mg |
| Palladium |
| 22,238-0 |
Allylpalladium chloride dimer |
100mg; 500mg; 5g |
| 22,565-7 |
Bis(acetonitrile)dichloropalladium(II), 99% |
500mg; 5g |
| 22,368-9 |
Bis(benzonitrile)dichloropalladium(II) |
250mg; 1g; 10g |
| 37,967-0 |
[1,1'-Bis(diphenylphosphino)ferrocene]
dichloropalladium(II), complex with CH2Cl2 |
1g; 5g |
| 40,323-7 |
Dichlorobis(tricyclohexylphosphine)palladium(II), 95% |
1g |
| 20,867-1 |
Dichlorobis(triphenylphosphine)palladium(II),98% |
1g; 5g; 25g |
| 45,304-8 |
Dichlorobis(tri-o-tolylphosphine)palladium(II),97% |
1g; 5g |
| 20,586-9 |
Palladium(II) acetate, 98% |
1g; 2g; 10g |
| 20,588-5 |
Palladium(II) chloride,99% |
1g; 5g; 25g |
| 21,666-6 |
Tetrakis(triphenylphosphine)palladium(0),99% |
1g; 5g; 25g |
| 32,877-4 |
Tris(dibenzylideneacetone)dipalladium(0) |
500mg; 5g |
| 36,631-5 |
Tris(dibenzylideneacetone)dipalladium(0)-CHCl3 adduct |
250mg; 1g |
| Phosphorus |
| 48,108-4 |
rac-6,6'-Bis(diphenylphosphino)-1,1'-binaphthyl,
97% (racemic-BINAP) |
5g; 25g |
| 29,581-7 |
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl,
97% [(R)-BINAP] |
100mg; 1g; 5g |
| 29,582-5 |
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl,
97% [(S)-BINAP] |
100mg; 1g; 5g |
| 52,646-0 |
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene,
97% (XANTPHOS) |
1g; 5g |
| 51,001-7 |
(Oxydi-2,1-phenylene)bis(diphenylphosphine),
98% (DPEphos) |
25g |
| 33,695-5 |
Tri-tert-butylphosphine, tech., 90% |
1g; 5g |
| 38,376-7 |
Tri-2-furylphosphine, 99% |
250mg; 1g |
| 44,179-1 |
Tris(2,4-di-tert-butylphenyl)phosphite, 98% |
100g; 500g |
| Rhenium |
| 41,291-0 |
Methyltrioxorhenium (VII) |
100mg; 500mg; 2g |
| Rhodium |
| 28,810-1 |
(Acetylacetonato)dicarbonylrhodium(I), 98% |
1g |
| 53,084-0 |
Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate,
98% |
1g |
| 22,795-1 |
Chloro(1,5-cyclooctadiene)rhodium(I) dimer, 98% |
500mg; 5g |
| 19,998-2 |
Chlorotris(triphenylphosphine)rhodium(I)
(Wilkinson's Catalyst) |
250mg; 1g; 5g |
| 20,905-8 |
Rhodium(II) acetate dimer |
50mg; 250mg; 1g |
| 20,626-1 |
Rhodium(III) chloride hydrate |
250mg; 1g; 5g |
| 20,903-1 |
Tetracarbonyldi-µ-chlorodirhodium(I), 97% |
250mg; 1g |
| Ruthenium |
| 33,500-2 |
Carbonyldihydridotris(triphenylphosphine)ruthenium(II) |
500mg; 1g; 5g |
| Samarium |
| 34,711-6 |
Samarium(II) iodide, 0.1M solution in tetrahydrofuran |
25mL; 100mL; 800mL |
| Scandium |
| 41,821-8 |
Scandium trifluoromethanesulfonate, 99% |
1g; 5g |
| Titanium |
| 23,482-6 |
Bis(cyclopentadienyl)titanium dichloride, 97% |
10g; 50g |
| Vanadium |
| 55,078-7 |
Vanadyl acetylacetonate,98% |
10g ; 50g |
| Zinc |
| 29,006-8 |
Zinc trifluoromethanesulfonate, 98% |
10g; 50g |
| Zirconium |
| 22,367-0 |
Bis(cyclopentadienyl)zirconium chloride hydride,
95% (Schwartz's Reagent) |
1g; 5g; 25g |
| 19,621-5 |
Bis(cyclopentadienyl)zirconium dichloride, 98+% |
5g; 25g; 100g |
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