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  Hot News  |  Latest ChemBlogs  |  New Literature  |   New Products  |  Technology Spotlights   April 2008


Welcome to ChemNews!

Our April ChemNews showcases over 40 brand NEW and innovative products for Asymmetric Synthesis and other new building blocks and reagents. In addition, we're featuring the latest literature for chemical synthesis available from Sigma-Aldrich, as well our latest product highlights — all easily accessed from one convenient location.

Make sure you subscribe to ChemNews — all ChemNews subscribers can download quarterly pdf and sdf files that contain all the new products added during the year.

Check out the categories to the right and click on the links to view the latest products in that category.

New Products
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Hot News

NEW! Cheminar 3.2
Formation of C–C Bonds via Catalytic Hydrogenation

New Cross-Coupling Application Portal
See our comprehensive portfolio of catalysts, reagents and reactants for cross-coupling compiled in a series of ChemFiles, Technology Highlights and ChemBlogs featuring examples of applications using these products.


Latest ChemBlogs


Mo-Phos: A New, Tri(tert-alkyl)phosphine Ligand for the Palladium-Catalyzed Amination of Haloarenes

An efficient and straightforward method for the direct amination of aryl halides has been developed by a team of researchers at Takasago International Corp. The method relies on the use of Mo-Phos, di-tert-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine, as a new, hybrid phosphine ligand for the palladium catalyst. Read More

Mo-Phos: A New, Tri(tert-alkyl)phosphine Ligand for the Palladium-Catalyzed Amination of Haloarenes


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New Literature


Allenes and Ionic Liquids in Asymmetric Synthesis
Vol. 40, No. 4
Allenes and Ionic Liquids in Asymmetric Synthesis

(3.95 Mb PDF)
Chemical Ligation
Vol. 8, No. 1
Chemical Ligation

(2.94 Mb PDF)
Cross-Coupling
Vol. 7, No. 10
Cross-Coupling

(3.45 Mb PDF)

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New Products

NEW catASium® Catalysts and Ligands
catASium is a registered trademark of Evonik Degussa GmbH

                       
669814 Structure Image

669814
670030 Structure Image

670030
670472 Structure Image

670472
669598 Structure Image

669598
 
669709 Structure Image

669709
669709 Structure Image

669709
669938 Structure Image

669938
670154 Structure Image

670154
 
670367 Structure Image

670367
670588 Structure Image

670588
 



NEW Organocatalysts

                       
693456 Structure Image 693561 Structure Image 693626 Structure Image 699320 Structure Image
 
693456
Asymmetric epoxidation organocatalyst
693561
Organocatalyst used in
the asymmetric reduction of
prochiral N-aryl ketimines


693626
Organocatalyst used in the
synthesis of chiral 1,2-diarylsubstituted aziridines


699320
Organocatalyst used in the addition of sulfonamides
to arylimines to form aminals
 
695718 Structure Image

695718

Organocatalyst used in asymmetric direct
alkylation of α-diazoesters
 



NEW Chiral Building Blocks

                       
685844 Structure Image

685844
685852 Structure Image

685852
671983 Structure Image

671983
672092 Structure Image

672092
 



NEW Takasago Catalyst Kits

                       
Takasago (R)-Ru
Cymene Kit I

695289
Takasago (R)-Ru
dimethylamine Kit I

695297
Takasago (R)-Ru
Acetate Kit I

695300
Takasago (R,R)-Ru
diamine Kit I

695319
 



Other NEW Phosphines

                       
694215 Structure Image 695599 Structure Image 695467 Structure Image 695459 Structure Image
 
694215
Ligand for asymmetric hydrogenation
695599
Bidentate ligand used for hydrogenation
695467
Air stable phosphine equivalent to tri-tert-butylphosphine, also efficient organocatalyst
695459
Air stable phosphine used in hydroformylation and cross coupling reactions
 
695149 Structure Image 672246 Structure Image 680451 Structure Image 695688 Structure Image
 
695149
Very potent ligand for Pd-catalyzed cross coupling
672246
cataCXium family ligand used for cross-coupling catalysis
680451
Pincer ligand used in a variety of coupling reactions
695688
Ligand used for arylation of heterocycles
 
694207 Structure Image

694207

NHC type ligand used for arylation
of amines and ketones
 



NEW Ketones

                       
696315 Structure Image

696315
690783 Structure Image

690783
684163 Structure Image

684163
692093 Structure Image

692093
 
692107 Structure Image

692107
679941 Structure Image

679941
694533 Structure Image

694533
694541 Structure Image

694541
 
691224 Structure Image

691224
 


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Technology Spotlights

ChiroSolv® Resolving Kits: Facile and Rapid Chiral Separation

ChiroSolv Kits Image



Takasago Ligands and Complexes for Asymmetric Reactions

Takasago Ligands and Complexes for Asymmetric Reactions


catASium®—Essential Elements for Asymmetric Hydrogenations

catASium-Essential Elements for Asymmetric Hydrogenations


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