Sigma-Aldrich
Chemistry

Chemical Synthesis
Product Catalog
Product Highlights
Key Resources
New Products Archive
Aldrichimica Acta
ChemFiles
ChemNews
Cheminars
ChemBlogs
Rxn Database
Technical Bulletins
ACS Awards
Drug Discovery
Materials Science
Stable Isotopes (ISOTEC)

 

 
  Hot News  |  Latest ChemBlogs  |  New Literature  |   New Products  |  Technology Spotlights   March 2008


Welcome to ChemNews!

Our March ChemNews showcases over 50 brand NEW and innovative products for C—C and C—X Bond Formation and other new reagents for chemical synthesis. In addition, we're featuring the latest literature for chemical synthesis available from Sigma-Aldrich, as well our latest product highlights — all easily accessed from one convenient location.

Make sure you subscribe to ChemNews — all ChemNews subscribers can download quarterly pdf and sdf files that contain all the new products added during the year.

Check out the categories to the right and click on the links to view the latest products in that category.

New Products
ChemBlogs Button

New Lab Start-Up Program Button


Hot News

NEW! Cheminar 3.1
Building a Better Cross Coupling Catalyst by Rational Design

New Cross-Coupling Application Portal
See our comprehensive portfolio of catalysts, reagents and reactants for cross-coupling compiled in a series of ChemFiles, Technology Highlights and ChemBlogs featuring examples of applications using these products.


Latest ChemBlogs


Silyl Chloride–N-Methylimidazole–Iodine: A Reagent System for the Efficient Silylation of Primary, Secondary, and Tertiary Alcohols

Stawinski and co-workers report that iodine exerts an accelerating effect on the silylation of alcohols in the presence of N-methylimidazole. This silylation is 5–30 times faster than the one that takes place under the standard Corey-Venkateswarlu silylation conditions. Read More

Silyl Chloride-N-Methylimidazole-Iodine: A Reagent System for the Efficient Silylation of Primary, Secondary, and Tertiary Alcohols


Back to Top

New Literature


Allenes and Ionic Liquids in Asymmetric Synthesis
Vol. 40, No. 4
Allenes and Ionic Liquids in Asymmetric Synthesis

(3.95 Mb PDF)
Chemical Ligation
Vol. 8, No. 1
Chemical Ligation

(2.94 Mb PDF)
Cross-Coupling
Vol. 7, No. 10
Cross-Coupling

(3.45 Mb PDF)

Back to Top

New Products

NEW Boron Reagents for Suzuki Coupling

                       
695661 Structure

695661
695009 Structure

695009
694991 Structure

694991
666947 Structure

666947
 
688290 Structure

688290
695866 Structure

695866
695629 Structure

695629
 



NEW Halogenated Heterocycles

                       
694266 Structure

694266
638145 Structure

638145
694738 Structure

694738
692298 Structure

692298
 
692549 Structure

692549
692557 Structure

692557
694711 Structure

694711
693944 Structure

693944
 
691852 Structure

691852
691739 Structure

691739
 



NEW Reagents for C—X Bond Formation

                       
694142 Structure

694142

Efficient reagent for
various bromination and
oxidation reactions
693332 Structure

693332

Mild and selective nucleophilic fluorination reagent for fluorination of alcohols and activated carbonyls
694207 Structure

694207

Ligand for catalytic
amination of
aryl chlorides
 

 
695882 Structure

695882
695262 Structure

695262
695211 Structure

695211
687243 Kit

687243
Buchwald ligands for C–C, C–N, and C–O bond formation
 



NEW Catalysts

                       
696617 Structure

696617

Pd catalyst for
Diels-Alder reactions
671916 Structure

671916

cataCXium® C catalyst for
C—X bond formation
685062 Structure

685062

C—H activation catalyst for preparation of phenols
695181 Structure

695181

Selective C-arylation catalyst for unprotected indoles and pyrrolidines
 



NEW Halogenated Aryl Substrates

                       
692107 Structure

692107
673846 Structure

673846
695394 Structure

695394
695386 Structure

695386
 
694827 Structure

694827
695351 Structure

695351
695343 Structure

695343
 



NEW NHC Ligands and Precursors

                       
696196 Structure

696196
693553 Structure

693553
693545 Structure

693545
688487 Structure

688487
 
668400 Structure

668400
 



NEW Phenethyl Bromides

                       
692050 Structure

692050
692042 Structure

692042
692034 Structure

692034
692026 Structure

692026
 
692018 Structure

692018
691992 Structure

691992
691984 Structure

691984
 


Back to Top

Technology Spotlights

Trost Ligands for Asymmetric Allylic Alkylation (AAA)

Headline graphic for Asymmetric Allylic Alkylation



Umicore Precatalysts for Asymmetric Reactions

Precatalysts for Asymmetric and Cross-Coupling Catalysis



(R)-(+)- and (S)-(–)-Stericol®: New, Effective Chiral Auxiliaries

Stericol Title Scheme


Click Here for more product highlights.

Subscribe/Unsubscribe to ChemNews.

Back to Top