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 Solvias Chiral Phosphine Ligands

The Ultimate Toolkit for Asymmetric Catalysis
 

Sigma-Aldrich, in collaboration with Solvias, is proud to present the Chiral Ligands Kit
– the ultimate toolkit for asymmetric catalysis!



The kit (Product No. 12000-1KT) is designed to allow rapid screening of chiral catalysts and consists of air-stable, non-hygroscopic, and industrially proven Solvias chiral phosphine ligand families.





40 different ligands and catalysts in 100 mg sample sizes, are available in both enantiomeric forms giving you access to a total of 80 products all in one convenient kit!

Online Ligand Database
Solvias provides an online guidance system based on a number of relevant industrial applications in order to find the perfect ligand for your specific application.
Learn more about the Ligands.

Included w/ Kit

  • CD ROM containing a comprehensive content list, Certificates of Analysis (CoA’s) and Material Safety Data Sheets (MSDS) for each product.
  • An IP flyer explaining Solvias’ particularly customer-friendly IP compensation model.
  • An extensive literature review organized by reaction type covering this unique class of privileged ligands completes this helpful tool.

Easy Reordering
All 80 ligands are available from Sigma-Aldrich individually in 100-mg, 500-mg, 1-g, and 5-g package sizes for facile reordering.



  Solvias Chiral Ligands Kit
  Josiphos Ligands
  Walphos Ligands
  Taniaphos Ligands
  MeOBIPHEP ligands
  Mandyphos Ligands
  Butiphane Catalysts
  Naud Catalysts

Solvias Chiral Ligands Kits
Product #  Product Name Add to Cart
12000 Solvias Chiral Ligands Kit purum, ≥97% (each component)
693367 Josiphos Ligands Kit I
693359 Mandyphos Ligands Kit I
693375 Walphos Ligands Kit I
696285 MeOBIPHEP Ligands Kit I
Josiphos Ligands
Product #  Product Name Add to Cart
88717 (R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct, purum
88718 (S)-1-[(1R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct, purum
88719 (R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine purum, ≥97.0% (CHN)
88720 (S)-1-[(1R)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine purum, ≥97.0% (CHN)
88721 (R)-1-[(1S)-2-Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine purum, ≥97.0% (CHN)
88722 (S)-1-[(1R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine purum, ≥97.0% (CHN)
88723 (R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-phenylphosphine purum purum, ≥97.0% (CHN)
88724 (S)-1-[(1R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-phenylphosphine purum, ≥97.0% (CHN)
88725 (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]-ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
88726 (S)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]-ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
88727 (R)-1-{(S)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-ferrocenyl}ethyldicyclohexylphosphine purum, ≥97%
88728 (R)-1-{(S)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-ferrocenyl}ethyldicyclohexylphosphine purum, ≥97%
88729 (R)-1-{(S)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine purum, ≥97.0% (CHN)
88730 (S)-1-{(R)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine purum, ≥97.0% (CHN)
88731 (R)-1-{(S)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-ferrocenyl}ethyldi(3,5-xylyl)phosphine purum
88732 (S)-1-{(R)-2-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-ferrocenyl}ethyldi(3,5-xylyl)phosphine purum, ≥97%
88733 (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyl­di-tert-butylphosphine purum, ≥97.0% (CHN)
88734 (S)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyl­di-tert-butylphosphine purum, ≥97.0% (CHN)
88735 (R)-1-{(S)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}-ethyldi-tert-butylphosphine purum, ≥97%
88736 (S)-1-{(R)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}-ethyldi-tert-butylphosphine purum, ≥97%
88737 (R)-1-[(S)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}ethyldi-tert-butylphosphine purum, ≥97.0% (CHN)
88738 (S)-1-[(R)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}ethyldi-tert-butylphosphine purum, ≥97.0% (CHN)
88739 (R)-1-{(S)-2-[Di(2-furyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
88740 (S)-1-{(R)-2-[Di(2-furyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
88741 (R)-1-{(S)-2-[Di(2-furyl)phosphino]ferrocenyl}ethyldi-tert-butylphosphine purum, ≥97.0% (CHN)
88742 (S)-1-{(R)-2-[Di(2-furyl)phosphino]ferrocenyl}ethyldi-tert-butylphosphine purum, ≥97.0% (CHN)
88743 (R)-1-{(S)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi-tert-butylphosphine purum, ≥97.0% (CHN)
88744 (S)-1-{(R)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi-tert-butylphosphine purum, ≥97.0% (CHN)
88745 (R)-1-{(S)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
88746 (S)-1-{(R)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
88747 (R)-1-{(S)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}-ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
88748 (S)-1-{(R)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}-ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
88749 (R)-1-{(S)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}-ethylbis(2-methylphenyl)phosphine purum, ≥97.0% (CHN)
88750 (S)-1-{(R)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}-ethylbis(2-methylphenyl)phosphine purum, ≥97.0% (CHN)
88751 (R)-1-{(S)-2-[Di(2-furyl)phosphino]ferrocenyl}ethylbis(2-methylphenyl)phosphine purum, ≥97.0% (CHN)
88752 (S)-1-{(R)-2-[Di(2-furyl)phosphino]ferrocenyl}ethylbis(2-methylphenyl)phosphine purum, ≥97.0% (CHN)
88753 (R)-1-[(S)-2-(Di-tert-butylphosphino)ferrocenyl]ethyldiphenylphosphine purum, ≥97.0% (CHN)
88754 (S)-1-[(R)-2-(Di-tert-butylphosphino)ferrocenyl]ethyldiphenylphosphine purum, ≥97.0% (CHN)
88755 (R)-1-[(S)-2-(Di-tert-butylphosphino)ferrocenyl]ethylbis(2-methylphenyl)phosphine purum, ≥97.0% (CHN)
88756 (S)-1-[(R)-2-(Di-tert-butylphosphino)ferrocenyl]ethylbis(2-methylphenyl)phosphine purum, ≥97.0% (CHN)
693367 Josiphos Ligands Kit I
Walphos Ligands back to top
Product #  Product Name Add to Cart
65671 (R)-1-{(R)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine purum, ≥97%
65672 (S)-1-{(S)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine purum, ≥97%
65673 (R)-1-{(R)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl}ethyldiphenylphosphine purum, ≥97.0% (CHN)
65674 (S)-1-{(S)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl}ethyldiphenylphosphine purum, ≥97.0% (CHN)
65675 (R)-1-{(R)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl}ethyldicyclohexylphosphine purum, ≥97.0% (CHN)
65676 (S)-1-{(S)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl}ethyldicyclohexylphosphine purum, ≥97.0% (CHN)
65677 (R)-1-{(R)-2-[2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]phenyl]ferrocenyl}-ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine purum, ≥97%
65678 (S)-1-{(S)-2-[2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]phenyl]ferrocenyl}-ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine purum, ≥97%
65679 (R)-1-{(R)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
65680 (S)-1-{(S)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
65681 (R)-1-{(R)-2-[2-(Dicyclohexylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine purum, ≥97%
65682 (S)-1-{(S)-2-[2-(Dicyclohexylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine purum, ≥97%
65683 (R)-1-{(R)-2-[2-[Di(3,5-xylyl)phosphino]phenyl]ferrocenyl}ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
65684 (S)-1-{(S)-2-[2-[Di(3,5-xylyl)phosphino]phenyl]ferrocenyl}ethyldi(3,5-xylyl)phosphine purum, ≥97.0% (CHN)
65685 (R)-1-{(R)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethyldi(2-norbornyl)phosphine purum, ≥97.0% (CHN)
65686 (S)-1-{(S)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethyldi(2-norbornyl)phosphine purum, ≥97.0% (CHN)
693375 Walphos Ligands Kit I
Taniaphos Ligands back to top
Product #  Product Name Add to Cart
07541 (S)-1-Diphenylphosphino-2-[(R)-a-(N,N-dimethylamino)-o-diphenylphosphinophenyl)methyl]ferrocene
07542 (R)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-diphenylphosphinophenyl)methyl]ferrocene
73475 (S)-1-Diphenylphosphino-2-[(R)-α-(dimethylamino)-2-(diphenylphosphino)benzyl]ferrocene purum, ≥97%
73476 (R)-1-Diphenylphosphino-2-[(S)-α-(dimethylamino)-2-(diphenylphosphino)benzyl]ferrocene purum, ≥97%
MeOBIPHEP ligands back to top
Product #  Product Name Add to Cart
(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-(diphenylphosphin)
(S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-(diphenylphosphin)
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(3,5-di-tert.-butyl-4-methoxyphenyl)-phosphin]
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(3,5-di-tert.-butyl-4-methoxyphenyl)-phosphin]
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-(di-2-furylphosphin)
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-(di-2-furylphosphin)
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(3,5-dimethylphenyl)-phosphin]
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(3,5-dimethylphenyl)-phosphin]
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-(diisopropylphosphin)
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-(diisopropylphosphin)
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(4-methylphenyl)-phosphin]
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(4-methylphenyl)-phosphin]
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(3,5-di-tert.-butylphenyl)-phosphin]
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(3,5-di-tert.-butylphenyl)-phosphin]
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(3,4,5-trimethoxyphenyl)-phosphin]
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-[bis-(3,4,5-trimethoxyphenyl)-phosphin]
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-{bis-[3,5-diisopropyl-4-(dimethylamino)-phenyl]-phosphin}
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)-bis-{bis-[3,5-diisopropyl-4-(dimethylamino)-phenyl]-phosphin}
696285 MeOBIPHEP Ligands Kit I
Mandyphos Ligands back to top
Product #  Product Name Add to Cart
73463 RR)-1,1′-Bis[α-(dimethylamino)benzyl]-(S,S)-2,2′-bis(diphenylphosphino)ferrocene purum, ≥97.0% (CHN)
73464 SS)-1,1′-Bis[α-(dimethylamino)benzyl]-(R,R)-2,2′-bis(diphenylphosphino)ferrocene purum, ≥97.0% (CHN)
73465 RR)-1,1′-Bis[α-(dimethylamino)benzyl]-(S,S)-2,2′-bis(dicyclohexylphosphino)ferrocene purum, ≥97.0% (CHN)
73466 SS)-1,1′-Bis[α-(dimethylamino)benzyl]-(R,R)-2,2′-bis(dicyclohexylphosphino)ferrocene purum, ≥97.0% (CHN)
73467 RR)-1,1′-Bis[α-(dimethylamino)benzyl]-(S,S)-,2′-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}ferrocene purum, ≥97%
73468 SS)-1,1′-Bis[α-(dimethylamino)benzyl]-(R,R)-,2′-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}ferrocene purum, ≥97%
73469 RR)-1,1′-Bis[α-(dimethylamino)benzyl]-(S,S)-2,2′-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene purum, ≥97.0% (CHN)
73470 SS)-1,1′-Bis-[α-(dimethylamino)benzyl]-(R,R)-2,2′-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene purum, ≥97.0% (CHN)
73471 RR)-1,1′-Bis[α-(dimethylamino)benzyl]-(S,S)-2,2′-bis[di(3,5-xylyl)phosphino]ferrocene purum, ≥97.0% (CHN)
73472 SS)-1,1′-Bis[α-(dimethylamino)benzyl]-(R,R)-2,2′-bis[di(3,5-xylyl)phosphino]ferrocene purum, ≥97.0% (CHN)
73473 RR)-1,1′-Bis[α-(dimethylamino)benzyl]-(S,S)-2,2′-bis[bis(2-methylphenyl)phosphino]ferrocene purum, ≥97.0% (CHN)
73474 SS)-1,1′-Bis[α-(dimethylamino)benzyl]-(R,R)-2,2′-bis[bis(2-methylphenyl)phosphino]ferrocene purum, ≥97.0% (CHN)
693359 Mandyphos Ligands Kit I
Butiphane Catalysts back to top
Product #  Product Name Add to Cart
53361 (R,R,R,R)-2,3-Bis(2,5-dimethyl-phospholanyl)benzo[b]thiophene cyclooctadiene rhodium(I) tetrafluoroborate Complex purum, ≥97%
53362 (S,S,S,S)-2,3-Bis(2,5-dimethyl-phospholanyl)benzo[b]thiophene cyclooctadiene rhodium(I) tetrafluoroborate Complex purum, ≥97%
Naud Catalysts back to top
Product #  Product Name Add to Cart
91991 (R)-2-[(R)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyl-2-oxazoline triphenylphosphine ruthenium(II) chloride Complex purum
91992 (S)-2-[(S)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyl-2-oxazoline triphenylphosphine ruthenium(II) dichloride Complex purum, ≥97.0%
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