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Analytical / Chromatography > Air Monitoring > Carbon Adsorbents > Physical Characteristics and Selection Guide
Carbon Adsorbents

Physical Characteristics and Selection Guide

Carbon Adsorbents main pageThe following information is gathered to assist chemists and method developers in locating the proper specialty carbon for their use. Additional assistance can be obtained by contacting our Technical Service group at techservice@sial.com.

Carbon Physical Characteristics – easy-to-use chart that shows the approximate surface area, pore volume, pore diameter, and free fall density for each of our specialty carbons

Carbon Cross-Reference – handy table to find replacements for carbons, including some that are discontinued

Carbon Selection Based on Analyte Size – bed order suggestions for multi-bed air monitoring tubes

A Tool for Selecting an Adsorbent for Thermal Desorption Applications – Technical Report with detailed adsorption/desorption characteristics of fifteen of our specialty carbons, plus nine other adsorbents


Carbon Physical Characteristics back to top

To view the approximate surface area, pore volume, pore diameter, and free fall density for each of our specialty carbons (Carbotrap™, Carbopack™, Carboxen™, Supelcarb™, and Carbosieve™), simply click the graphic below. If you are unable to download this, contact Technical Service at techservice@sial.com.

Carbon Adsorbent Physical Characteristics
Carbon Physical Characteristics

(18Kb PDF)

Carbon Cross-Reference back to top

Use this handy cross-reference table to find our equivalents or substitutions for commonly used carbon adsorbents, including some that are discontinued.


Carbon Our Equivalent or Substitute
Ambersorb 347 Carboxen 564
Ambersorb 563 Carboxen 563
Ambersorb 572 Carboxen 572
Anasorb CMS Carboxen 564, Carboxen 1000, Carbosieve S-III
Anasorb CSC Activated (coconut) charcoal
Anasorb GCB1 Carbotrap B, Carbopack B
Anasorb GCB2 Carbotrap C, Carbopack C
Anasorb 747 Carboxen 564, Carboxen 1000, Carbosieve S-III
Carbograph 1 Carbotrap B, Carbopack B
Carbograph 2 Carbotrap C, Carbopack C
Carbosphere Carboxen 1000
Graphpac-GC Carbotrap B, Carbopack B
Purosieve Carboxen 1000
Spherocarb Carboxen 1000


Carbon Selection Based on Analyte Size back to top

When working with multi-bed air monitoring tubes, use the weaker adsorbents in front to protect the stronger adsorbents. This prevents analytes from becoming strongly retained on the stronger adsorbents, resulting in poor analyte release during the chemical or thermal desorption process. The table below shows relative adsorptive strengths for our specialty carbon materials. As an example, use Carbopack C in front of Carbopack B.


Analyte
Size (1)
Adsorptive
Strength
Adsorptive Strength
(Weakest - - - - - - - - - - - - - - - - - - - - - - - - - - - - - > Strongest)
>C14 Weakest
|
|
|
|
|
|

Strongest
Carbotrap/Carbopack F
C12-C20 Carbotrap/Carbopack C
C9-C14 Carbotrap/Carbopack Y
C5-C12 Carbotrap/Carbopack B, Carboxen 1017, Carboxen 1016
C3-C9 Carbopack Z, Carbotrap/Carbopack X
C2-C5 Carboxen 569, Carboxen 1001, Carboxen 1012, Carboxen 1000, Carboxen 572, Carboxen 1006, Carbosieve S-II, Carbosieve G, Carbosieve S-III, Carboxen 1003, Supelcarb, Carboxen 563, Carboxen 564, Carboxen 1018, Carboxen 1010, Carboxen 1021

1. Analyte size relative to n-alkanes. Consider all atoms, not just carbon. For example, even though 1,2-dichloroethane is a C2, the two chlorine atoms give it a relative size between C4 and C5.


A Tool for Selecting an Adsorbent for Thermal Desorption Applications back to top
Detailed adsorption/desorption characteristics of fifteen of our specialty carbons plus nine other adsorbents, depicted in twenty-four easy-to-follow color-coded tables, are shown in A Tool for Selecting an Adsorbent for Thermal Desorption Applications (T402025 HTA). To download your no-charge copy of this Technical Report, simply click the graphic of the report cover. If you are unable to download this, contact Technical Service at techservice@sial.com. selecting adsorbents for thermal desorption
(288Kb PDF)