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Air Monitoring
Vapor Intrusion Monitoring
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Supelco has the complete analytical solution for Vapor Intrusion monitoring and analysis. We offer a wide range of products including sampling media, solvents, thermal desorption tubes, Tedlar® air sampling bags, pumps, chemical standards (second source available), GC columns, and HPLC columns. We can help you find the right products to retain and analyze those difficult vapor intrusion compounds with our high-quality adsorbents developed by our experts in carbon and adsorbent technology. Cannot find a product that fits your needs? Review our custom capabilities.
| What is Vapor Intrusion? |
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| Vapor Intrusion is defined as vapor phase migration of volatile organic (VOC’s) and/or inorganic compounds into indoor air spaces of occupied buildings from underlying contaminated ground water and/or soil. The resulting air quality problem from these vapors can pose a health risk to the occupants. Assessment of Vapor Intrusion sites typically includes a “multiple lines of evidence” sampling approach which involves sampling indoor and ambient air, soil gases, and groundwater sites. |
| Contaminants of Interest |
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- Benzene, Toluene, Ethylbenzene, and Xylenes (BTEX)
- Volatile Organic Compounds (VOC’s) – polar, non-polar, chlorinated – Tetrachloroethylene (PCE –“Perc”), Trichloroethylene (TCE), Vinyl Chloride (VC), cis-1,2-Dichloroethene (DCE), Total Petroleum Hydrocarbons (TPH), Methyl tert-Butyl Ether (MTBE)
- Polynuclear Aromatic Hydrocarbons (PAH’s)
- Polychlorinated Biphenyls (PCB’s) and Pesticides
- Other common contaminants: Aldehydes, Ketones, and Acetone
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| Products - Air Sampling Media and Standards |
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Products are organized by Contaminants of Interest and US EPA Method
| Air Sampling Applications |
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Indoor Air For residential and commercial building owners alike, one concern is regarding the indoor air quality. Could the indoor air be polluted? If so, it is often difficult to determine the source because many factors could play a role in indoor air pollution besides vapor intrusion, such as background or pre-existing levels of pollutants from chemical use in the building – cleaning agents, paints and solvents, new carpeting and building materials, etc or from outdoor (ambient) air entering the building. If vapors do enter a building, the contaminant levels are usually very low and pose no immediate risk. Health problems associated with indoor vapor intrusion are commonly due to long-term exposure to low levels of these chemicals, which are proving to be dangerous to adults and especially to children. Typical sample collection times to assess this contamination are 24-hours for residential site sampling and 8 to 12 hours for commercial site sampling.
In the same context as Vapor Intrusion, Sick Building Syndrome (SBS) and Building Related Illness (BRI) are of concern. Sick Building Syndrome describes a situation where building occupants experience health related problems but no specific cause can be determined, while Building Related Illness associates the health related problems with a diagnosable illness thata can be attributed directly to airborne contaminants. In both cases, the causes are typically associated with poor HVAC systems, off-gassing of building materials, lack of adequate air filtration, and mold.
Supelco provides the full range of air sampling products to address Indoor Vapor Intrusion , Sick Building Syndrome , and Building Related Illness.
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Advantages of passive (diffusive) sampling over active methods in Indoor Air sampling:
- Ease of application, silent operation
- No expensive equipment required
- No leak testing required for soil gas
- Lower reporting limits achievable compared to SUMMA canisters (i.e., 0.18 µg/m3 for benzene with a radiello® sampler over a 7-day sampling period as compared to 3.4 µg/m3 for 1-liter canister by standard TO-15 analysis)
- Lower breakthrough/saturation for equivalent sample volumes
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Ambient Air Sampling In addition to indoor air pollution testing, it is necessary to perform ambient (outdoor) site testing to determine the chemical concentration from outside sources. Sample collection in this case is typically 24-hours. The same contaminants of interest are addressed for both indoor and ambient sampling. In order to determine the contribution of outdoor to indoor contaminants, the outdoor air concentration is subtracted from the indoor air concentration to exclude any outdoor sources from the vapor intrusion evaluation. This is necessary to exclude unrelated outdoor sources from the evaluation. |
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Soil Gas/Vapor Sampling Soil is a vapor intrusion pollutant pathway and therefore is included in vapor intrusion studies. Soil gas monitoring provides a quick evaluation of waste site conditions, which can help identify the source of contamination, and its movement through the soil.
In order to sample soil gas, a hole must be driven into the ground by means of a drive rod and inserting a probe into this hole. The air sample is pulled from this probe into the collection device.
Supelco offers Tedlar® bags as a collection device for soil gas samples, and the vacuum pump to draw the vapor into the bag.
Soil Gas Micro-wells Monitoring for VOC’s can also be achieved by inserting the radiello passive sampling device into the drive hole (see figure below). Sampling may be limited due to cartridge exposure to moisture or if airflow starved – less than 0.2 m/sec velocity.
Crawl Space Monitoring radiello samplers provide an advantage over TO-17 and canisters due to their sensitivity and ability to achieve measurement of low concentrations of contaminants of interest.
Soil Gas: Micro-well
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Soil Gas: Crawl Space
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| (photos provided courtesy: DMS Environmental Services, LLC) |
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