Carboxen® Adsorbents

Our Carboxen Carbon Molecular Sieve (CMS) materials have through-pore structures. That is, the majority of the pores pass entirely through the particles. Additionally, the specially designed pores taper from macro- to meso- to micropores, resulting in materials with excellent thermodynamic properties for both adsorption and desorption processes. As such, no other CMS materials on the market can match the performance of our Carboxen materials. When protected properly with weaker adsorbents upstream, the Carboxen materials provide great performance for a very wide range of small C2-C5 analytes.

Fifteen Carboxen materials are offered:
  • Carboxen 563 is useful for collecting volatile organic compounds (VOCs) from water or air.
  • Carboxen 564 is effective for collecting VOCs from air. It has a greater capacity than Carboxen 563.
  • Carboxen 569 is a highly hydrophobic material, making it useful for sampling in high humidity environments. Relative to Carboxen 563 and Carboxen 564, Carboxen 569 has a greater capacity for organic molecules and a lower capacity for water.
  • Carboxen 572 is a highly efficient CMS material and compares directly to Carboxen 1000. The primary difference between Carboxen 572 and Carboxen 1000 is the particle size distribution (Carboxen 572 is only available in 20/45 mesh whereas Carboxen 1000 is available in 40/60, 60/80, and 80/100 mesh).
  • Carboxen 1000 has a large surface area and optimized microporosity, which enable it to effectively and efficiently adsorb and desorb smaller molecular size compounds, providing excellent chromatography without a need for cryogenic cooling. One of our most efficient CMS materials, it is widely used in purge traps and air sampling media. It is also used for low volume sampling of very volatile compounds, such as vinyl chloride.
  • Carboxen 1001 is used to trap and retain very small compounds. It is often used as the final bed in multi-bed adsorbent tubes, to minimize breakthrough. It is similar to Carboxen 569 in strength and hydrophobicity. Note that bulk Carboxen 1001 material is only available as a custom item.
  • Carboxen 1003, with a large surface area and hydrophobic surface characteristics, provides a desirable combination of efficient adsorption/desorption and good hydrophobicity.
  • Carboxen 1005 material is based on Carboxen 1003 material. With twice the trapping ability compared to active charcoal, it is primarily used in gas purification applications to retain hydrocarbons. Note that bulk Carboxen 1005 material is only available as a custom item.
  • Carboxen 1006 is only available as 2 μm particles. It is used as an adsorbent in porous layer open tubular (PLOT) capillary GC columns. Note that bulk Carboxen 1006 material is only available as a custom item.
  • Carboxen 1010, also only available as 2 μm particles, is used as an adsorbent in PLOT capillary GC columns. Note that bulk Carboxen 1010 material is only available as a custom item.
  • Carboxen 1012 is a highly activated, inert CMS possessing large mesopores. It can be used effectively for aqueous phase adsorption of organic compounds, or for air sampling of C4-C6 compounds. Note that bulk Carboxen 1012 material is only available as a custom item.
  • Carboxen 1016 is unlike most other CMSs because it is non-porous. Its adsorptive strength it slightly stronger than that of Carboxen 1017.
  • Carboxen 1017 is also non-porous. With the weakest adsorptive strengths of our CMSs, it provides a unique bridge between the GCB and CMS materials. This highly engineered material has traveled to space on several missions, used to collect samples for evolved gas analysis. Note that bulk Carboxen 1017 material is only available as a custom item.
  • Carboxen 1018, possessing a large percentage of narrow (6-7 Å) micropores, is useful for the adsorption/desorption of small analytes, such as C2 (ethane, ethylene, acetylene) and C3 hydrocarbons. This hydrophobic, inert, and strong adsorbing porous carbon can be used in sampling tubes to collect ethane, acetaldehyde, and other small molecules present in exhaled breath samples. Note that bulk Carboxen 1018 material is only available as a custom item.
  • Carboxen 1021 is another highly-microporous CMS designed for air sampling of small molecules. It is similar to Carboxen 1018 in that is has a large percentage of small micropores. Compared to Carboxen 1018, it has smaller micropores (5-6 Å), and is more hydrophobic. Note that bulk Carboxen 1021 material is only available as a custom item.

While these carbon materials are stable to above 400 °C, the temperature actually used at depends on the application. For example, thermal desorption unit (TDU) tubes are typically desorbed at 330 °C, purge traps containing just carbons typically use a 250 °C desorption temperature, and GC column applications may work best with final oven temperatures of 225 °C. For assistance in determining the proper temperature for your application, contact Technical Service at techservice@sial.com

Product #

Description

Add to Cart

10263 Carboxen® Adsorbent matrix Carboxen® 563, 20-45 mesh, bottle of 10 g
10264 Carboxen® Adsorbent matrix Carboxen® 564, 20-45 mesh, bottle of 10 g
11324-U Carboxen® Adsorbent matrix Carboxen® 564, 20-45 mesh, pack of 144 × 290 mg
10269 Carboxen® Adsorbent matrix Carboxen® 569, 20-45 mesh, bottle of 10 g
11048-U Carboxen® Adsorbent matrix Carboxen® 569, 20-45 mesh, bottle of 500 g
11072-U Carboxen® Adsorbent matrix Carboxen® 572, 20-45 mesh, bottle of 10 g
10477-U Carboxen® Adsorbent matrix Carboxen® 1000, 40-60 mesh, bottle of 50 g
10478-U Carboxen® Adsorbent matrix Carboxen® 1000, 60-80 mesh, bottle of 10 g
10471 Carboxen® Adsorbent matrix Carboxen® 1003, 40-60 mesh, bottle of 10 g
11021-U Carboxen® Adsorbent matrix Carboxen® 1016, 60-80 mesh, bottle of 10 g