Return to Web Version
Sigma-Aldrich
Analytical / Chromatography > Gas Chromatography > Capillary GC Columns > Astec CHIRALDEX > CHIRALDEX PN
Gas Chromatography

CHIRALDEX PN

Astec Products | Technical Resources  | Chiral Services
Ordering Information

Astec CHIRALDEX G-PN capillary GC columns incorporate a phase consisting of a 2,6-di-O-pentyl-3-propionyl derivative of γ-cyclodextrin. This phase exhibits high selectivity for lactones and aromatic amines. It is also suitable for epoxide separations. Additionally, the analysis of styrene oxide can be accomplished on this phase (this analyte degrades on the TA phases).


Type / Name Derivative γ-Phase Max. Temp.(°C)
Isothermal
Max. Temp.(°C)
Programmed
PN / Propionyl 2,6-di-O-pentyl-3-propionyl G-PN 200 220

Features

  • Suitable for epoxide separations
  • High selectivity for lactones
  • High selectivity for aromatic amines (i.e. amphetamine, methamphetamine)
  • More stable to moisture than the TA phases

Mechanism Observations

There is little evidence of inclusion formation. Retention increases with increased chain length of analyte. This allows for efficient separation of a series of homologs.


Size Selectivity

The G-PN shows very little size selectivity.


Specific Classes of Compounds Separated

Use this table as a reference to help determine the proper column based on the analyte(s) of interest.

Type Compound Class
G-PN Epoxides, secondary amines, higher alcohols >C4, esters, lactones, and diols.


 

your favorite gene search

powered by ingenuity

Service & Support
Ordering
Corporate

©2011 Sigma-Aldrich Co. LLC. All rights reserved. SIGMA, SAFC, SIGMA-ALDRICH, ALDRICH, and SUPELCO are trademarks of Sigma-Aldrich Co. LLC, registered in the US and other countries. FLUKA is a trademark of Sigma-Aldrich GmbH, registered in the US and other countries. Sigma brand products are sold through Sigma-Aldrich, Inc. Purchaser must determine the suitability of the product(s) for their particular use. Additional terms and conditions may apply. Site Use Terms | Privacy

  • YouTube
  • Twitter
  • LinkedIN
  • Facebook