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The Journal of organic chemistry

Ligand effects on the stereochemical outcome of Suzuki-Miyaura couplings.


PMID 22480237

Abstract

The ligands associated with various Pd catalysts play a crucial role in determining the stereochemistry of cross-couplings between boronic acids and Z-alkenyl halides. A ligand on palladium has been found that leads to the desired products under mild conditions and in high yields that, in most cases, retain their Z-olefin geometry.

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436836
2-Thienylboronic acid, ≥95.0%
C4H5BO2S