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Chemistry, an Asian journal

Remazol-Catalyzed Hydroperoxyarylation of Styrenes.


PMID 26084245

Abstract

A mild photocatalytic hydroperoxyarylation of styrenes has been developed, in which a novel photocatalyst, remazol brilliant blue R (RBBR), is employed at low catalytic loading (1 mol %). The operationally easy procedure uses air as the dioxygen source. Simple mono-substituted styrenes react with aryl hydrazines in moderate-to-good yields. RBBR is proposed to act as a photosensitizer for the generation of singlet oxygen.

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R8001
Remazol Brilliant Blue R, anthraquinone dye
C22H16N2Na2O11S3