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174645 Aldrich

2-Methoxypropene

97%

Synonym: Isopropenyl methyl ether

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Properties

Related Categories Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents More...
vapor pressure   27.96 psi ( 55 °C)
  8.28 psi ( 20 °C)
assay   97%
autoignition temp.   374 °F
refractive index   n20/D 1.382(lit.)
bp   34-36 °C(lit.)
density   0.753 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

50, 250 g in glass bottle

Application

Used to protect adjacent hydroxyls in inositols as bisacetonides,1 and 1,2-diols in general.2

Price and Availability

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2-Methoxypropene

analytical standard

2-Methoxypropene

produced by BASF, ≥98.0% (GC)

2-Methoxypropene-d<SUB>8</SUB>

90 atom % D

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
May form explosive peroxides.
Hazard Codes (Europe) 
Risk Statements (Europe) 
Safety Statements (Europe) 
3-7/9-16-29-33
RIDADR 
UN 1993A 3 / PGI
WGK Germany 
1
RTECS 
UD0800000
Flash Point(F) 
-18.4 °F
Flash Point(C) 
-28 °C

Protocols & Articles

Peer-Reviewed Papers

References

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1. J. Am. Chem. Soc. 115, 4429, (1993)

2. Greene, T.W. Wuts, P.G.M. Protective Groups in Organic Synthesis 3rd ed., New York , (1991), 124

Beil. 1,IV,2075

Fieser 2,230 / Fieser 5,360 / Fieser 12,317

Aldrich MSDS 1, 1195:D / Corp MSDS 1 (2), 2271:B / FT-IR 2 (1), 318:B / FT-IR 1 (1), 213:A / FT-NMR 1 (1), 334:A / IR-Spectra (3), 128:C / NMR-Reference 2 (1), 181:B / RegBook 1 (1), 219:I / Structure Index 1, 30:D:5 / Vapor Phase 3, 279:C

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