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656763 - Di-μ-chlorotetraethylene dirhodium(I)

656763 Aldrich

Di-μ-chlorotetraethylene dirhodium(I)

Synonym: Bis[chlorobis(ethylene)rhodium], Bis[chlorodiethylenerhodium], Chlorobis(ethylene)rhodium dimer, Dichlorotetra(ethene)dirhodium, Dichlorotetrakis(ethene)dirhodium, Diethylenerhodium chloride dimer, Divinylrhodium chloride dimer, Tetrakis(ethylene)dichlorodirhodium, [Rh(C₂H₄)₂Cl]₂

CAS Number 12081-16-2
Empirical Formula (Hill Notation) C₈H₁₆Cl₂Rh₂
Molecular Weight 388.93
EC Number 235-145-0
MDL number MFCD00013206
PubChem Substance ID 24884230
Popular Documents: Specification Sheet (PDF)

Properties

Related Categories	Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium More...
storage temp.	−20°C

Description

Application

Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones.¹

Packaging

1 g in glass bottle

100 mg in glass bottle

Price and Availability

Articles

Asymmetric Conjugate Addition

In the past 5 years, chiral diene ligands have surfaced for a variety of asymmetric transformations. Hayashi1 and Carreira2 pioneered this field by synthesizing chiral diene ligands that formed stabl...
William Sommer
Aldrich ChemFiles 2008, 8.6, 11.
Keywords: Addition reactions, Arylations, Asymmetric synthesis, Building blocks, Catalysis, Ligands

Asymmetric Hydrosilylation

The asymmetric hydrosilylation of olefins has proven to be a useful method to access a variety of chiral alcohols.1 The introduction of the silica moiety allows further transformation of the molecule...
William Sommer
Aldrich ChemFiles 2008, 8.6, 4.
Keywords: Asymmetric synthesis, Hydrosilylations, Ligands, transformation

Carreira DOLEFIN Ligands

For the past years, the Carreira group has been employing chiral [2.2.2]bicyclooctadienes derived from (R)- or (S)-carvone in Ir(I)-catalyzed kinetic resolution of allylic carbonates1 and Rh(I)-catal...
Aldrich ChemFiles 2006, 6.10, 4.
Keywords: Addition reactions, Asymmetric synthesis, Catalysis, Infrared spectroscopy, Ligands

Palladium-Catalyzed Reduction of Allylic Esters

The palladium catalyzed reduction of allylic esters provides a convenient method to access chiral olefins.1Hayashi et al. studied the activity of the MOP ligand with palladium toward the reduction of...
William Sommer
Aldrich ChemFiles 2008, 8.6, 4.
Keywords: Catalysis, Ligands, Reductions

Papers

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1. Tetrahedron 63, 12961, (2007)

Fieser 5,203

Aldrich MSDS 1, 640:D / Corp MSDS 1 (1), 1168:A / FT-IR 2 (3), 4512:C / FT-IR 1 (2), 1236:B / RegBook 1 (2), 3075:A / Structure Index 1, 487:B:7

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