Potassium allyltrifluoroborate 95%

Properties

Related Categories	Alkyl Trifluoroborate Salts, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Trifluoroborate Salts More...
assay	95%
mp	>300 °C

Description

Packaging

1 g in poly bottle

Application

Organotrifluoroborate involved in:
• Catalytic allylboration¹
• Stereoselective nucleophilic addition²
• Pd-catalyzed heterocyclizations³
• Oxidation reactions⁴ and Oxidative Mannich reactions⁵
• Cross-coupling reactions⁶

Organotrifluoroborates as versatile and stable boronic acid surrogates.

Protocols & Applications

Suzuki Cross-Coupling using Organotrifluoroborates as Potent Boronic Acid Surrogates

Price and Availability

Related Papers

1. Catalytic activation of pinacolyl allylboronate with indium(I): development of a general catalytic allylboration of ketones U. Schneider and S. Kobayashi, Angew. Chem. Int. Ed. Engl. 46, 5909-5912, (2007)

Documents

Certificate of Analysis

ChemFiles Vol 7 No 7 (1 MB )

Safety Information

Symbol	GHS05, GHS07
Signal word	Danger
Hazard statements	H315-H318-H335
Precautionary statements	P261-P280-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes (Europe)	Xi
Risk Statements (Europe)	37/38-41
Safety Statements (Europe)	26-36/39
WGK Germany	3

Technical information & documentation associated with this product is available in the Safety & Documentation tab.

Papers

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1. Catalytic activation of pinacolyl allylboronate with indium(I): development of a general catalytic allylboration of ketones U. Schneider and S. Kobayashi, Angew. Chem. Int. Ed. Engl. 46, 5909-5912, (2007)

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2. Stereoselective nucleophilic addition of potassium alkyltrifluoroborates to cyclic N-acyliminium ions: a simple and mild approach to chiral 5-alkylpyrrolidin-2-ones A. S. Vieira, et al., Aust. J. Chem. 62, 909-916, (2009)

3. Pd-catalysed regioselective C-H functionalisation of 2-pyrones M. J. Burns, et al., Dalton Trans. 39, 10391-10400, (2010)

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4. Oxidation of Alkyl Trifluoroborates: an Opportunity for Tin-Free Radical Chemistry G. Sorin, et al., Angew. Chem. Int. Ed. Engl. 49, 8721-8723, (2010)

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5. The development of a Selectfluor-mediated oxidative Mannich reaction M. H. Daniels and J. Hubbs, Tetrahedron Lett. 52, 3543-3546, (2011)

6. A new organic transformation by introducing crotyl/allyltrifluoroborates in cross-coupling reaction with aroyl chlorides M. Al-Masum and K. Liu, Tetrahedron Lett. 52, 5090-5093, (2011)