661007 Aldrich

Hydroxy[-(S)-BINAP]-rhodium(I) Dimer

90%

DOWNLOAD MSDS (PDF)
  • Empirical Formula (Hill Notation) C88H66O2P4Rh2

  • Molecular Weight 1485.17

  •  MDL number MFCD08561132

  •  PubChem Substance ID 24884495

Properties

Related Categories Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Conjugate Addition,
assay   90%
impurities   3-5% THF
  3-5% ethanol

Description

Application

Catalyst employed in an asymmetric 1,6-addition of arylzinc reagents to dienones leading to chiral 5-substituted enones.1 Also used in an asymmetric 1,4-addition of organoboron reagents to cyclic and acyclic α,β-unsaturated ketones with excellent enantioselectivity.2

Efficient and Selective Catalysts for Asymmetric Synthesis

Packaging

1 g in glass bottle

250 mg in glass bottle

Price and Availability

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