|Related Categories||Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Conjugate Addition,|
Catalyst employed in an asymmetric 1,6-addition of arylzinc reagents to dienones leading to chiral 5-substituted enones.1 Also used in an asymmetric 1,4-addition of organoboron reagents to cyclic and acyclic α,β-unsaturated ketones with excellent enantioselectivity.2
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In the late 1990s, the Hayashi group successively developed rhodium-based catalysts applied in the asymmetric, conjugate addition of arylboronic acids to C=C bonds.1 They utilized Rh-BINAP catalysts ...
ChemFiles Volume 5 Article 10
Keywords: Addition reactions, Asymmetric synthesis, Catalysis, Natural product synthesis, Rearrangements, Reductions, Solvents, transformation
The Hayashi group at Kyoto University has spearheaded the development of rhodium-based catalysts applied in the asymmetric, conjugate addition of arylboronic acids to C=C bonds.1 They utilized Rh-BIN...
Keywords: Addition reactions, Asymmetric synthesis, Building blocks, Catalysis, Eliminations
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