|Related Categories||Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Jacobsen Thioureas|
|optical activity||[α]20/D -57.0°, c = 1 in chloroform|
Versatile catalyst for reactions including the Mannich reaction.1
100, 500 mg in glass bottle
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|Precautionary statements||P261-P280-P305 + P351 + P338|
|Personal Protective Equipment||dust mask type N95 (US), Eyeshields, Gloves|
|Hazard Codes (Europe)||Xn|
|Risk Statements (Europe)||20/21/22-36/37/38|
|Safety Statements (Europe)||26-36/37|
New Versatile Organocatalysts In 2002, Jacobsen’s group first reported the application of thiourea organocatalyst 1 (693421) in the asymmetric Strecker reaction. Since that initial report, Jacobsen's...
Keywords: Asymmetric synthesis, Catalysis, Chromatography, Hydrocyanations, Hydrophosphonylations, Mannich Reaction, Organic synthesis, Pictet-Spengler reaction, Strecker synthesis
1. Divergent Stereoinduction Mechanisms in Urea-Catalyzed Additions to Imines Wenzel, A.G.; Lalonde, M.P.; Jacobsen, E.N. Synlett, 1919, (2003)
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