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693731 Aldrich

Samarium

foil, thickness 1 mm, 99.9% trace rare earth metals basis

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Properties

Related Categories 62: Sm, Catalysis and Inorganic Chemistry, Chemical Synthesis, Magnetic Materials, Magnetic Precursors,
assay   99.9% trace rare earth metals basis
form   foil
resistivity   91.4 μΩ-cm, 0°C
thickness   1 mm
bp   1794 °C(lit.)
mp   1074 °C(lit.)
density   7.47 g/mL at 25 °C(lit.)

Description

Application

Used in Physical Vapor Deposition (PVD) processes, including thermal and electron-beam (e-beam) evaporation, for the preparation of thin films.

Packaging

1 ea in rigid mailer

Quantity

1 ea = 25 x 25 mm

Price and Availability

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Hazard Codes (Europe) 
Risk Statements (Europe) 
Safety Statements (Europe) 
16-30-33
RIDADR 
UN 2910 7
WGK Germany 
3

Protocols & Articles

Articles

Metal Hydrides for NiMH Battery Applications

Rechargeable solid-state batteries are becoming increasingly important due to wide-spread use in computers, portable electronics, and vehicular applications. The Partnership for a New Generation of V...
Dhanesh Chandra,* Wen-Ming Chien and Anjali Talekar
Material Matters Volume 6 Article 2
Keywords: Absorption, Applications, Automotive, Capillary electrophoresis, Combustion, Degradations, Electrochemical analysis, Electronics, Environmental, Help, Ion-exchange chromatography, Phase transitions, Precipitation, Purification, Separation, Substitutions, Type

Peer-Reviewed Papers

References

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Systemic administration of new therapeutic radioisotopes, including phosphorus, strontium, samarium, and rhenium. Porter AT, Ben-Josef E, and Davis L Curr. Opin. Oncol. 6(6), 607-10, (1994)

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Total synthesis of clavilactone B: a radical cyclization-fragmentation strategy. Suizu H, Shigeoka D, Aoyama H, et al. Org. Lett. 17(1), 126-9, (2015)

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Preparation and use of samarium diiodide (SmI(2)) in organic synthesis: the mechanistic role of HMPA and Ni(II) salts in the samarium Barbier reaction. Sadasivam DV, Choquette KA, and Flowers RA J. Vis. Exp. (72), e4323, (2013)

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Spectroscopic and laser properties of Sm³⁺ ions doped lithium fluoroborate glasses for efficient visible lasers. Zulfiqar Ali Ahamed S, Madhukar Reddy C, and Deva Prasad Raju B Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 103, 246-54, (2013)

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Samarium Sm-153 lexidronam for the palliation of bone pain associated with metastases. Serafini AN Cancer 88(12 Suppl), 2934-9, (2000)

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Solvent dependent reductive defluorination of aliphatic C-F bonds employing Sm(HMDS)2. Janjetovic M, Träff AM, Ankner T, et al. Chem. Commun. (Camb.) 49(18), 1826-8, (2013)

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Evidence of a structural phase transition in superconducting SmFeAsO(1-x)F(x) from 19F NMR. Majumder M, Ghoshray K, Mazumdar C, et al. J. Phys. Condens. Matter 25(2), 025701, (2013)

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Hydrothermal synthesis of NaLuF4:153Sm,Yb,Tm nanoparticles and their application in dual-modality upconversion luminescence and SPECT bioimaging. Yang Y, Sun Y, Cao T, et al. Biomaterials 34(3), 774-83, (2013)

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Samarium(II)-iodide-mediated cyclizations in natural product synthesis. Edmonds DJ, Johnston D, and Procter DJ Chem. Rev. 104(7), 3371-404, (2004)

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Samarium diiodide mediated reactions in total synthesis. Nicolaou KC, Ellery SP, and Chen JS Angew. Chem. Int. Ed. Engl. 48(39), 7140-65, (2009)

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Biodistribution of sub-10 nm PEG-modified radioactive/upconversion nanoparticles. Cao T, Yang Y, Sun Y, et al. Biomaterials 34(29), 7127-34, (2013)

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Samarium diiodide induced ketyl-(het)arene cyclisations towards novel N-heterocycles. Beemelmanns C and Reissig HU Chem. Soc. Rev. 40(5), 2199-210, (2011)

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Selective reductive transformations using samarium diiodide-water. Szostak M, Spain M, Parmar D, et al. Chem. Commun. (Camb.) 48(3), 330-46, (2012)

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Photo-induced self-cleaning and sterilizing activity of Sm3+ doped ZnO nanomaterials. Saif M, Hafez H, and Nabeel AI Chemosphere 90(2), 840-7, (2013)

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All-fiber passively Q-switched fiber laser with a Sm-doped fiber saturable absorber. Lu Y and Gu X Opt. Express 21(2), 1997-2002, (2013)

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Utilizing Tb3+ as an energy transfer bridge to connect Eu(2+)-Sm3+ luminescent centers: realization of efficient Sm3+ red emission under near-UV excitation. Jia Y, Lü W, Guo N, et al. Chem. Commun. (Camb.) 49(26), 2664-6, (2013)

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Systemic metabolic radiotherapy with samarium-153 EDTMP for the treatment of painful bone metastasis. Serafini AN Q. J. Nucl. Med. 45(1), 91-9, (2001)

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Effect of the crystal structure of small precursor particles on the growth of β-NaREF4 (RE = Sm, Eu, Gd, Tb) nanocrystals. Voß B, Nordmann J, Uhl A, et al. Nanoscale 5(2), 806-12, (2013)

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Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium. Concellón JM, Rodríguez-Solla H, Concellón C, et al. Chem. Soc. Rev. 39(11), 4103-13, (2010)

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Beta-elimination reactions by using samarium diiodide. Concellón JM and Rodríguez-Solla H Chem. Soc. Rev. 33(9), 599-609, (2004)

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Selective synthesis of α,α-dideuterio alcohols by the reduction of carboxylic acids using SmI2 and D2O as deuterium source under SET conditions. Szostak M, Spain M, and Procter DJ Org. Lett. 16(19), 5052-5, (2014)

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Sm(3+)-doped Ba3Bi(PO4)3 orange reddish emitting phosphor. Yang F, Yang Z, Yu Q, et al. Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 105, 626-31, (2013)

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Isolation and crystallographic characterization of Sm@C2v(3)-C80 through cocrystal formation with Ni(II)(octaethylporphyrin) or bis(ethylenedithio)tetrathiafulvalene. Yang H, Wang Z, Jin H, et al. Inorg. Chem. 52(3), 1275-84, (2013)

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Optical and luminescent properties of Sm³+ doped tellurite glasses. Sasikala T, Rama Moorthy L, and Mohan Babu A Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 104, 445-50, (2013)

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Investigation of spectroscopic properties, structure and luminescence spectra of Sm3+ doped zinc bismuth silicate glasses. Pal I, Agarwal A, Sanghi S, et al. Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 101, 74-81, (2013)

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Enantioselective total synthesis of the diterpene (+)-cubitene. Simon K, Wefer J, Schöttner E, et al. Angew. Chem. Int. Ed. Engl. 51(43), 10889-92, (2012)

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Synergism and inhibition in the combination of visible light and HMPA in SmI2 reductions. Rao CN and Hoz S J. Org. Chem. 77(20), 9199-204, (2012)

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Samarium for osteoblastic bone metastases and osteosarcoma. Anderson P Expert Opin. Pharmacother. 7(11), 1475-86, (2006)

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Access to an unexplored chiral C82  cage by encaging a divalent metal: structural elucidation and electrochemical studies of Sm@C2(5)-C82. Xu W, Niu B, Feng L, et al. Chemistry 18(45), 14246-9, (2012)

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Evidence for supernova injection into the solar nebula and the decoupling of r-process nucleosynthesis. Brennecka GA, Borg LE, and Wadhwa M Proc. Natl. Acad. Sci. U. S. A. 110(43), 17241-6, (2013)

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Recent advances in the chemistry of SmI(2)-H(2)O. Sautier B and Procter DJ Chimia 66(6), 399-403, (2012)

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Samarium lexidronam (153Sm-EDTMP): skeletal radiation for osteoblastic bone metastases and osteosarcoma. Anderson P and Nuñez R Expert Rev. Anticancer Ther. 7(11), 1517-27, (2007)

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Structural anomalies related to changes in the conduction mechanisms of α-Sm2(MoO4)3. Guzmán-Afonso C, González-Silgo C, Torres ME, et al. J. Phys. Condens. Matter 25(3), 035902, (2013)

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Targeted "bone-seeking" radiopharmaceuticals for palliative treatment of bone metastases: a systematic review and meta-analysis. D'angelo G, Sciuto R, Salvatori M, et al. Q. J. Nucl. Med. Mol. Imaging 56(6), 538-43, (2012)

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Bone-targeted agents: preventing skeletal complications in prostate cancer. Morgans AK and Smith MR Urol. Clin. North Am. 39(4), 533-46, (2012)

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A study on the magnetic and photoluminescence properties of Eu(n+) and Sm3+ doped Fe3O4 nanoparticles. Huan W, Cheng C, Yang Y, et al. J. Nanosci. Nanotechnol. 12(6), 4621-34, (2012)

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Dual-label time-resolved fluoroimmunoassay for simultaneous quantification of haptoglobin and C-reactive protein in meat juice from pigs. Gutiérrez AM, Cerón JJ, Marsilla BA, et al. Can. J. Vet. Res. 76(2), 136-42, (2012)

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Cyclizations producing hydrindanones with two methyl groups at the juncture positions mediated by samarium diiodide and electrolysis. Sono M, Ise N, Shoji T, et al. Molecules 17(9), 11079-88, (2012)

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Anomalous magnetic behavior of Sm0.8Ca0.2MnO3 nanoparticles. Mogilyansky D, Fita I, Wisniewski A, et al. J. Nanosci. Nanotechnol. 12(11), 8613-8, (2012)

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A prospective randomized trial: a comparison of the analgesic effect and toxicity of 153Sm radioisotope treatment in monotherapy and combined therapy including local external beam radiotherapy (EBRT) among metastatic castrate resistance prostate cancer (mCRPC) patients with painful bone metastases. Baczyk M, Milecki P, Pisarek M, et al. Neoplasma 60(3), 328-33, (2013)

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[Rapid reduction of a variety of organic functionalities including a new selective reduction with samarium diiodide]. Kamochi Y and Kudo T Yakugaku Zasshi 120(3), 245-55, (2000)

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[6-endo-trig mode cyclization to a hydrindanone using samarium (II) iodide]. Sono M Yakugaku Zasshi 123(8), 653-63, (2003)

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Merck 14,8347

Aldrich MSDS 1, 1596:A / Aldrich MSDS 1, 1596:B / Corp MSDS 1 (2), 3067:D / Corp MSDS 1 (2), 3067:C / RegBook 1 (3), 3231:N / RegBook 1 (3), 3231:M / Sax 6, 2382

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