• USA Home
  • 261939 - 1,2-Bis(dimethylphosphino)ethane

EMAIL THIS PAGE TO A FRIEND

261939 Aldrich

1,2-Bis(dimethylphosphino)ethane

97%

Synonym: DMPE, Dimethyl-2-(dimethylphosphino)ethylphosphine, Ethylenebis(dimethylphosphine)

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands
assay   97%
refractive index   n20/D 1.507(lit.)
bp   180 °C(lit.)
density   0.9 g/mL at 25 °C(lit.)

Description

Packaging

1, 5 g in ampule

Application

1,2-Bis(dimethylphosphino)ethane (dmpe) may be employed as ligand in the preparation of cis-arylmethyl(dmpe) nickel(II) complexes.1

General description

1,2-Bis(dimethylphosphino)ethane (dmpe) is a polydentate phosphine ligand. Synthesis of 1,2-bis(dimethylphosphino)ethane has been reported.2 It reacts with ZrCl2 to afford ZrCl4(dmpe)2 complexes.3

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993BF 3 / PGII
WGK Germany 
3

Protocols & Articles

Peer-Reviewed Papers

References

Set your institution to view full text papers.

1. Phosphine-induced reductive elimination from cis-arylmethylnickel (II) complexes having a 1,2-bis(dimethylphosphino) ethane ligand Komiya S, et al. Organometallics 2(10), 1466-68, (1983)

2. A convenient synthesis of 1, 2-bis (dichlorophosphino) ethane, 1, 2-bis (dimethylphosphino) ethane and 1,2-bis (diethylphosphino) ethane. Burt RJ, et al. J. Organomet. Chem. 182(2), 203-6, (1979)

3. Beatty RP, et al. Inorg. Chem. 18(11), 3139-45, (1979)

Beil. 4,IV,3439

Aldrich MSDS 1, 198:D / Corp MSDS 1 (1), 431:D / RegBook 1 (1), 1087:D / Structure Index 1, 168:C:1 / Vapor Phase 3, 837:B

Related Products

accessory

Product #

Description

Add to Cart

Z693847 Scienceware® Break-Safe ampule opener

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?