|Related Categories||Asymmetric Synthesis, Chemical Synthesis, Chiral Auxiliaries, Oxazolidinone Derivatives|
|optical activity||[α]/D -75±5°, c = 0.2 in chloroform|
|optical purity||enantiomeric ratio: 97.0:3.0 (LC)|
A highly selective and efficient chiral auxiliary1 which can be directly reduced to its corresponding aldehyde and the chiral auxiliary by reductive cleavage with diisobutylaluminum hydride.2
The asymmetric aldol reaction mediated by chiral auxiliaries is considered to be one of the most important methods for asymmetric C-C bond formation. Chiral oxazolidinethiones and thiazolidinethiones...
Keywords: Addition reactions, Aldol condensation, Aldol reaction, Asymmetric synthesis, C-C bond formation, Chiral auxiliaries, Condensations, Transaminations, transformation
1. Velàzquez. F.; Olivo, H. F. Current Org. Chem. 6, 303, (2002)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Need larger quantities for your development, manufacturing or research applications?