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02615 Aldrich

(Ethoxycarbonylmethyl)triphenylphosphonium chloride

technical, ≥90% (AT)

Synonym: (2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride

  • CAS Number 17577-28-5

  • Linear Formula CH3CH2OCOCH2P(Cl)(C6H5)3

  • Molecular Weight 384.84

  •  Beilstein Registry Number 3924139

  •  EC Number 241-548-2

  •  MDL number MFCD00011746

  •  PubChem Substance ID 24845340

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents More...
InChI Key   DJGHVEPNEJKZBF-UHFFFAOYSA-M
grade   technical
assay   ≥90% (AT)
mp   120-123 °C (dec.)
  120-123 °C(lit.)
storage temp.   2-8°C

Description

Other Notes

Starting material for preparing the Wittig-reagent

Application

Reactant for:
• Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression
• Ring-opening reactions with Wittig reagents
• Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation
• Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions
• Preparation of phosphonium derivatives of coumarin

Price and Availability

Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.



Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles
Peer-Reviewed Papers
15

References

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