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107840 Aldrich

2,2,2-Trifluoroacetophenone

99%

Synonym: α,α,α-Trifluoroacetophenone, Phenyl trifluoromethyl ketone

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Properties

Related Categories Building Blocks, C7 to C8, Carbonyl Compounds, Chemical Synthesis, Ketones,
InChI Key   KZJRKRQSDZGHEC-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.458(lit.)
bp   165-166 °C(lit.)
  46-48 °C/14 mmHg(lit.)
density   1.24 g/mL at 25 °C(lit.)

Description

Packaging

5, 25, 100 g in glass bottle

Application

2,2,2-Trifluoroacetophenone was used in the synthesis of new fluorinated polymers, having high average molecular weight, high thermal stability and good film-forming properties.

General description

2,2,2-Trifluoroacetophenone is the starting material for the synthesis of f 3-trifluoromethyl-3-phenyldiazirine. It undergoes asymmetric reduction with optically active Grignard reagent to form 2,2,2-trifluoro-1-phenylethanol. It undergoes condensation with biphenyl, terphenyl, a mixture of biphenyl with terphenyl, phenyl ether and diphenoxybenzophenone to form new aromatic 3F polymers.

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN1224 - class 3 - PG 3 - Ketones, liquid, n.o.s., HI: all
WGK Germany 
3
Flash Point(F) 
105.8 °F
Flash Point(C) 
41 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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