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10892 Aldrich

Ethyl 3-(4-methoxyphenyl)-3-oxopropionate

produced by Wacker Chemie AG, Burghausen, Germany, ≥97.0% (GC)

Synonym: Ethyl 4-methoxybenzoylacetate, MOBEE

  • CAS Number 2881-83-6

  • Empirical Formula (Hill Notation) C12H14O4

  • Molecular Weight 222.24

  •  Beilstein Registry Number 979481

  •  EC Number 220-733-1

  •  MDL number MFCD00449636

  •  PubChem Substance ID 57646828

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Properties

Related Categories Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis, Esters,
grade   produced by Wacker Chemie AG, Burghausen, Germany
InChI Key   KRAHENMBSVAAHD-UHFFFAOYSA-N
assay   ≥97.0% (GC)
mfr. no.   Wacker Chemie AG
bp   154 °C/1 hPa(lit.)
solubility   H2O: soluble
density   1.160 g/mL at 20 °C(lit.)

Description

Other Notes

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General description

Ethyl 3-(4-methoxyphenyl)-3-oxopropionate is a yellow to very dark yellow liquid or viscous liquid. It undergoes one-pot two-step sequential reaction involving arylhydrazines, β-ketone esters, formaldehyde and styrenes in glycerol. It undergoes Pechmann condensation with resorcinol and 2-methylresorcinol to form 7-hydroxy-4-(4-methoxyphenyl)coumarin and 7-hydroxy-8-methyl-4-(4-methoxyphenyl)coumarin respectively.

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Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
239 °F
Flash Point(C) 
115 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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