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108995 Aldrich

Methyl thioglycolate

95%

Synonym: Methyl mercaptoacetate

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Properties

Related Categories Building Blocks, Catalysis and Inorganic Chemistry, Chemical Synthesis, Organic Building Blocks, Photocatalysis,
InChI Key   MKIJJIMOAABWGF-UHFFFAOYSA-N
assay   95%
refractive index   n20/D 1.466(lit.)
bp   42-43 °C/10 mmHg(lit.)
density   1.187 g/mL at 25 °C(lit.)

Description

Packaging

5, 100, 500 g in glass bottle

Application

Methyl thioglycolate was used in the preparation of:
• 3-carbomethoxy-4- oxotetrahydrothiopyran, 2- and 4-carbomethoxy-3-oxotetrahydrothiophene
• methyl thioglycolate and aminoethanethiol conjugated gold nanorods.

Thiol Organocatalyst used in conjunction with visible light photocatalysis to affect the direct arylation of benzylic ether C-H bonds

A General Strategy for Organocatalytic Activation of C–H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers

General description

Methyl thioglycolate reacts with nonprotein component of the antitumor antibiotic neocarzinostatin to form 1:1 adduct. It reacts with isothiocyanate to form Rhodanine.

Price and Availability


Laboratory Gloves
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 1992 6.1(3) / PGIII
WGK Germany 
1
RTECS 
AI7350000
Flash Point(F) 
132.8 °F
Flash Point(C) 
56 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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