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108995 Aldrich

Methyl thioglycolate

95%

Synonym: Methyl mercaptoacetate

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Properties

Related Categories Building Blocks, Catalysis and Inorganic Chemistry, Chemical Synthesis, Organic Building Blocks, Photocatalysis,
InChI Key   MKIJJIMOAABWGF-UHFFFAOYSA-N
assay   95%
refractive index   n20/D 1.466(lit.)
bp   42-43 °C/10 mmHg(lit.)
density   1.187 g/mL at 25 °C(lit.)

Description

Packaging

5, 100, 500 g in glass bottle

Application

Methyl thioglycolate was used in the preparation of:
• 3-carbomethoxy-4- oxotetrahydrothiopyran, 2- and 4-carbomethoxy-3-oxotetrahydrothiophene
• methyl thioglycolate and aminoethanethiol conjugated gold nanorods.

Thiol Organocatalyst used in conjunction with visible light photocatalysis to affect the direct arylation of benzylic ether C-H bonds

A General Strategy for Organocatalytic Activation of C–H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers

General description

Methyl thioglycolate reacts with nonprotein component of the antitumor antibiotic neocarzinostatin to form 1:1 adduct. It reacts with isothiocyanate to form Rhodanine.

Price and Availability

Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.



Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 1992 6.1(3) / PGIII
WGK Germany 
1
RTECS 
AI7350000
Flash Point(F) 
132.8 °F
Flash Point(C) 
56 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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