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109207 Aldrich

2-Methyl-2-propanethiol

99%

Synonym: tert-Butyl mercaptan, TBM

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Properties

Related Categories Alkyl Thiols, Building Blocks, Chemical Synthesis, Materials Science, Micro/NanoElectronics,
vapor density   3.1 (vs air)
vapor pressure   303.5 mmHg ( 37.7 °C)
InChI Key   WMXCDAVJEZZYLT-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.423(lit.)
bp   62-65 °C(lit.)
mp   -0.5 °C(lit.)
solubility   H2O: slightly soluble
  alcohol: very soluble
  diethyl ether: very soluble
density   0.8 g/mL at 25 °C(lit.)

Description

Packaging

100, 500 mL in Sure/Seal™

2 L in Sure/Seal™

Application

2-Methyl-2-propanethiol was used in reaction of 2-methyl-2-propanethiol on Mo(110) using temperature programmed reaction, high resolution electron enegy loss and X-ray photoelectron spectroscopies. It was used in the synthesis of chain-transfer agents for reversible addition-fragmentation chain-transfer copolymerization of vinylidene chloride and methyl acrylate.

General description

2-Methyl-2-propanethiol undergoes ring opening nucleophilic reaction with 3-isothiazolones and reaction kinetics studies suggested reaction was second order in thiol and third order overall.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2347 3 / PGII
WGK Germany 
3
RTECS 
TZ7660000
Flash Point(F) 
-13 °F
Flash Point(C) 
-25 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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