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122068 Aldrich

trans-4-Methoxy-3-buten-2-one

technical grade, 90%

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Properties

Related Categories Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones,
grade   technical grade
InChI Key   VLLHEPHWWIDUSS-ONEGZZNKSA-N
assay   90%
refractive index   n20/D 1.468(lit.)
bp   200 °C(lit.)
density   0.982 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

10, 50, 250 g in glass bottle

Application

trans-4-Methoxy-3-buten-2-one was used as starting reagent for enantioselective total synthesis of (-)-epibatidine.

General description

trans-4-Methoxy-3-buten-2-one acts as substrate and undergoes zinc triflate-catalyzed Mukaiyama-Michael reaction with 3-TBSO-substituted vinyldiazoacetate to yield functionalized 3-keto-2-diazoalkanoates.

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
145.4 °F
Flash Point(C) 
63 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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08168 Timestrip Plus 8 °C

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