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122831 Aldrich

2-Aminobenzyl alcohol

98%

Synonym: 2-(Hydroxymethyl)aniline

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Properties

Related Categories Amino Alcohols, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds More...
InChI Key   VYFOAVADNIHPTR-UHFFFAOYSA-N
assay   98%
bp   162 °C/15 mmHg(lit.)
mp   81-83 °C(lit.)

Description

Packaging

10, 25 g in glass bottle

Application

2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.

General description

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.

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Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
RTECS 
DN3155000
Protocols & Articles
Peer-Reviewed Papers
15

References

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