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124168 Aldrich

2-Bromothiophene

98%

Synonym: 2-Thienyl bromide

  • CAS Number 1003-09-4

  • Empirical Formula (Hill Notation) C4H3BrS

  • Molecular Weight 163.04

  •  Beilstein Registry Number 104663

  •  EC Number 213-699-4

  •  MDL number MFCD00005417

  •  PubChem Substance ID 24847601

  • Popular Documents:  FTIR (PDF)  

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Properties

Related Categories Building Blocks, C4 to C6, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks,
InChI Key   TUCRZHGAIRVWTI-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.586(lit.)
bp   149-151 °C(lit.)
density   1.684 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

10, 50, 250 g in glass bottle

Application

2-Bromothiophene has been used in electrochemical reduction of a number of mono- and dihalothiophenes at carbon cathodes in dimethylformamide containing tetramethylammonium perchlorate by cyclic voltammetry and controlled-potential electrolysis.

General description

2-Bromothiophene undergoes metalation-alkylation reaction with various electrophiles to form various 5-alkylated 2-bromo products. It undergoes coupling with 4-bromo allyl phenyl ether to form allyl phenyl thiophene ether, which is a novel potential dielectric material for organic thin film transistors.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2929 3(6.1) / PGII
WGK Germany 
3
Flash Point(F) 
125.6 °F
Flash Point(C) 
52 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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