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125415 Aldrich

1,4-Cyclohexadiene

97%

Synonym: 1,4-Dihydrobenzene

  • CAS Number 628-41-1

  • Empirical Formula (Hill Notation) C6H8

  • Molecular Weight 80.13

  •  Beilstein Registry Number 1900733

  •  MDL number MFCD00001535

  •  PubChem Substance ID 24847665

  • Popular Documents:  FTNMR (PDF)  

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Properties

Related Categories Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Organic Building Blocks More...
InChI Key   UVJHQYIOXKWHFD-UHFFFAOYSA-N
assay   97%
contains   ~0.1% hydroquinone as stabilizer
impurities   3% benzene
refractive index   n20/D 1.472(lit.)
bp   88-89 °C(lit.)
density   0.847 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

5, 25, 100 mL in glass bottle

Application

1,4-Cyclohexadiene (1,4-CHD) was used to study the formation of parent ion from heavy fragmentation of 1,4-CHD on irradiation with a high-intensity laser pulse.

General description

1,4-Cyclohexadiene is an effective hydrogen donor for catalytic hydrogenation reactions. It can rapidly replace benzyl groups of N-benzyloxycarbamates, benzyl esters, benzyl ethers and benzyl amines with hydrogen. It forms benzene at elevated temperatures in the presence of a ruthenium(II)-triphenylphosphine catalyst.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3295BF 3 / PGII
WGK Germany 
3
Flash Point(F) 
19.4 °F
Flash Point(C) 
-7 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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