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128554 Aldrich

1,5-Hexadiene

97%

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Properties

Related Categories Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks More...
vapor pressure   367 mmHg ( 37.7 °C)
InChI Key   PYGSKMBEVAICCR-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.404(lit.)
bp   60 °C(lit.)
mp   −141 °C(lit.)
density   0.692 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

25, 100 g in ampule

Application

1,5-Hexadiene was used to study the Pd(II)-catalyzed cycloisomerization of functionalized 1,5-hexadienes.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2458 3 / PGII
WGK Germany 
3
RTECS 
MM1997800
Flash Point(F) 
-16.6 °F
Flash Point(C) 
-27 °C
Protocols & Articles

Articles

MRT - Ring Closure — Synthesis of Methylenecyclopentane

The cyclization of 1,5-hexadiene to exo-methylenecyclopentane (251356) poses multiple challenges: the batch reaction affords an inseperable mixture of the endo- and exo-cyclization product (Scheme 6)...
Matthias Junkers
Aldrich ChemFiles 2009, 9.4, 14.
Keywords: Chemfiles, Continuous flow chemistry, Cyclizations, Isomerizations, Microreactor technology, Separation, transformation

MRT - Staudinger Hydration

Benefit from MRT & Flow Chemistry: Efficient phase transfer catalysis; safe & scale-independent handling of explosive intermediates in small hold-up volumes with instant conversion.
Matthias Junkers
Aldrich ChemFiles 2009, 9.4, 14.
Keywords: Calorimetry, Catalysis, Chemfiles, Continuous flow chemistry, Hydration reaction, Microreactor technology, Nucleophilic substitutions, Phase transfer catalysis, Substitutions

Peer-Reviewed Papers
15

References

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Z693847 Scienceware® Break-Safe ampule opener

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94791 SnapIT Ampule Opener, Regular, for 1-2ml, 5-10ml, 10-15ml ampoules
43917 SnapIT Ampule Opener, large, for 5-10ml, 10-15ml, 20-25ml ampoules

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