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136255 Aldrich

2-Methyl-4(5)-nitroimidazole

99%

  • CAS Number 696-23-1

  • Empirical Formula (Hill Notation) C4H5N3O2

  • Molecular Weight 127.10

  •  Beilstein Registry Number 4032

  •  EC Number 211-790-3

  •  MDL number MFCD00151322

  •  PubChem Substance ID 24848270

  • Popular Documents:  FTIR (PDF)  

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Properties

Related Categories Building Blocks, C3 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Imidazoles More...
assay   99%
mp   251-255 °C(lit.)

Description

Packaging

50, 250 g in poly bottle

Application

2-Methyl-4(5)-nitroimidazole was used to study the mechanism of both the alkaline and acidic hydrolysis of tinidazole1.

Price and Availability


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1-<WBR>Methyl-<WBR>5-<WBR>nitroimidazole

>97.0% (HPLC)

2-<WBR>Methyl-<WBR>5-<WBR>nitroimidazole

pharmaceutical secondary standard; traceable to USP and PhEur

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
Hazard Codes (Europe) 
Xn
Risk Statements (Europe) 
22
WGK Germany 
3
RTECS 
NI7550000
Flash Point(F) 
383 °F
Flash Point(C) 
195 °C

Protocols & Articles

Peer-Reviewed Papers

References

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1. On the hydrolytic behavior of tinidazole, metronidazole, and ornidazole. Salo JP, Yli-Kauhaluoma J, and Salomies H J. Pharm. Sci. 92(4), 739-46, (2003)

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Radicals of nitroimidazole derivatives: pH dependence of rates of formation and decay related to acid-base equilibria. Henry Y, Guissani A, and Hickel B Int. J. Radiat. Biol. Relat. Stud. Phys. Chem. Med. 51(5), 797-809, (1987)

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[Synthesis and antibacterial activity of ciprofloxacin derivatives]. Ye FQ, Ding YM, Chen L, et al. Yao Xue Xue Bao 40(2), 132-5, (2005)

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[Synthesis and antibacterial activity of pyridonecarboxylic acid derivatives containing 2-methyl-5-nitroimidazol]. Ye FQ, Chen L, and Huang JM Yao Xue Xue Bao 38(4), 260-3, (2003)

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[Determination of acid-base amphoteric dissociation constant of 2-methyl-5 (4)-nitroimidazole by UV-spectrophotometry]. Yang S Hua Xi Yi Ke Da Xue Xue Bao 30(3), 345-6, (1999)

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Synthesis of 3'-azolyl-2',3'-dideoxyhexose nucleosides. Walczak K, Pedersen EB, and Nielsen C Acta Chem. Scand. 52(7), 935-41, (1998)

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Evaluation of 99mTc(CO)3 complex of 2-methyl-5-nitroimidazole as an agent for targeting tumor hypoxia. Mallia MB, Subramanian S, Banerjee S, et al. Bioorg. Med. Chem. 14(23), 7666-70, (2006)

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A comparative study on vibrational, conformational and electronic structure of 1,2-dimethyl-5-nitroimidazole and 2-methyl-5-nitroimidazole. Arjunan V, Ravindran P, Santhanam R, et al. Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 97, 176-88, (2012)

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The identification and assay of 2-methyl-5-nitroimidazole in pigs treated with dimetridazole. Carignan G, Carrier K, and Sved S Food Addit. Contam. 8(4), 467-75, (1991)

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Radiosynthesis and evaluation of two novel 123I-labeled 2-methyl-4-nitroimidazole derivatives as potential infection imaging agents. Rossouw DD, Lötter MG, du Raan H, et al. Nucl. Med. Biol. 32(4), 385-94, (2005)

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Beil. 23,I,23

FT-IR 2 (3), 3514:B / FT-IR 1 (2), 618:D / IR-Spectra (3), 1221:A / IR-Spectra (2), 1063:A / NMR-Reference 2 (2), 490:B / RegBook 1 (2), 2359:C / Sax 6, 1887 / Structure Index 1, 373:B:5

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