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  • 13730 - (2R,3S)-(+)-3-(Benzyloxymethyl)oxirane-2-methanol 4-nitrobenzoic acid ester

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13730 Aldrich

(2R,3S)-(+)-3-(Benzyloxymethyl)oxirane-2-methanol 4-nitrobenzoic acid ester

≥99.0% (sum of enantiomers, HPLC)

Synonym: (2R,3S)-(+)-4-Benzyloxy-2,3-epoxy-1-butyl 4-nitrobenzoate

  • CAS Number 78469-86-0

  • Empirical Formula (Hill Notation) C18H17NO6

  • Molecular Weight 343.33

  •  Beilstein Registry Number 5383515

  •  MDL number MFCD00043126

  •  PubChem Substance ID 57647111

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks More...
InChI Key   XBAOYRZETQXAAE-DLBZAZTESA-N
assay   ≥99.0% (sum of enantiomers, HPLC)
optical activity   [α]20/D +34±1°, c = 0.5% in chloroform
mp   78-80 °C

Description

Other Notes

Stable precursor to (2R,3S)-(+)-3-(benzyloxymethyl)oxirane-2-methanol which is a versatile chiral building block ; Nucleophilic substitution at carbon C-1 ; Cuprous iodide catalyzed addition of Grignard reagents at C-2

Packaging

5 g in glass bottle

Price and Availability


Laboratory Gloves
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles
Peer-Reviewed Papers
15

References

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