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  • 13730 - (2R,3S)-(+)-3-(Benzyloxymethyl)oxirane-2-methanol 4-nitrobenzoic acid ester

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13730 Aldrich

(2R,3S)-(+)-3-(Benzyloxymethyl)oxirane-2-methanol 4-nitrobenzoic acid ester

≥99.0% (sum of enantiomers, HPLC)

Synonym: (2R,3S)-(+)-4-Benzyloxy-2,3-epoxy-1-butyl 4-nitrobenzoate

  • CAS Number 78469-86-0

  • Empirical Formula (Hill Notation) C18H17NO6

  • Molecular Weight 343.33

  •  Beilstein Registry Number 5383515

  •  MDL number MFCD00043126

  •  PubChem Substance ID 24848319

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks More...
InChI Key   XBAOYRZETQXAAE-DLBZAZTESA-N
assay   ≥99.0% (sum of enantiomers, HPLC)
optical activity   [α]20/D +34±1°, c = 0.5% in chloroform
mp   78-80 °C

Description

Other Notes

Stable precursor to (2R,3S)-(+)-3-(benzyloxymethyl)oxirane-2-methanol which is a versatile chiral building block ; Nucleophilic substitution at carbon C-1 ; Cuprous iodide catalyzed addition of Grignard reagents at C-2

Packaging

5 g in glass bottle

Price and Availability

Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.



Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles
Peer-Reviewed Papers
15

References

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