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140066 Aldrich

1,3,5-Tribromobenzene

98%

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Properties

Related Categories Aryl, Building Blocks, C6, Chemical Synthesis, Halogenated Hydrocarbons,
assay   98%
bp   271 °C(lit.)
mp   117-121 °C(lit.)

Description

Packaging

25, 100 g in glass bottle

General description

• 1,3,5-Tribromobenzene(TBB) acts as internal standard during derivatization step in determination of cyanide in human plasma and urine by gas chromatography-mass spectrometry1.
• TBB forms molecular complexes of 1:2 stoichiometry with [60]-and [70] fullerenes2.
• TBB reacts with perfluoroalkenylzinc reagent in the presence of Pd(Ph3)4 catalyst to yield a novel trifunctional monomer 1,3,5-tris(α, β, β-trifluorovinyl)benzene3.

Price and Availability

Safety & Documentation

Safety Information

Hazard statements 
Risk Statements (Europe) 
53
WGK Germany 
3

Protocols & Articles

Peer-Reviewed Papers

References

Set your institution to view full text papers.

1. Rapid determination of cyanide in human plasma and urine by gas chromatography-mass spectrometry with two-step derivatization. Liu G, Liu J, Hara K, et al. J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 877(27), 3054-8, (2009)

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2. A comparative study of molecular complexation of [60]- and [70]fullerenes with 1,3,5-tribromobenzene by UV-vis spectrophotometric method. Datta K and Mukherjee AK Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 62(1-3), 66-70, (2005)

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3. A novel 1,3,5-tris(alpha,beta,beta-trifluorovinyl)benzene monomer. Ford LA and DesMarteau DD Chem. Commun. (Camb.) (20), 2596-7, (2003)

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Extractive alkylation and gas chromatographic analysis of sulfide. Kage S, Nagata T, Kimura K, et al. J. Forensic Sci. 33(1), 217-22, (1988)

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[Solid phase microextraction and derivatization of sulfide in blood with pentafluorobenzylbromide]. Liu J, Tan F, Feng X, et al. Wei Sheng Yan Jiu 32(6), 620-1, (2003)

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Synthesis and properties of a new type DNA dendrimer. Suzuki Y, Otomo T, Ozaki H, et al. Nucleic Acids Symp. Ser. (44), 125-6, (2000)

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Hepatotoxicity of brominated benzenes: relationship between chemical structure and hepatotoxic effects in acute intoxication of mice. Szymańska JA Arch. Toxicol. 72(2), 97-103, (1998)

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Beil. 5,IV,685

Aldrich MSDS 1, 1727:B / Corp MSDS 1 (2), 3392:D / FT-IR 1 (1), 1008:D / FT-IR 2 (2), 1724:C / FT-NMR 1 (2), 117:C / IR-Spectra (2), 539:E / IR-Spectra (3), 606:A / NMR-Reference 2 (1), 808:B / RegBook 1 (1), 1193:N / Structure Index 1, 183:A:4 / Vapor Phase 3, 937:B

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