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140414 Aldrich

3,5-Di-tert-butyl-2-hydroxybenzaldehyde

99%

Synonym: 3,5-Di-tert-butylsalicylaldehyde

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Properties

Related Categories Aldehydes, Building Blocks, C13-C60, Carbonyl Compounds, Chemical Synthesis,
InChI Key   RRIQVLZDOZPJTH-UHFFFAOYSA-N
assay   99%
mp   59-61 °C(lit.)

Description

Packaging

25 g in poly bottle

5 g in glass bottle

Application

3,5-Di-tert-butyl-2-hydroxybenzaldehyde was used in the synthesis of
• Mn(III)-salen complex and its diamino precursor 5,6-diamino-5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-β-L-idofuranose
• chiral Schiff base ligand for an enantioselective copper-catalyzed addition of phenylacetylene to imines
• chiral oxazolidine ligand for the enantioselective addition of diethylzinc to aldehydes
• tin Schiff base complexes with histidine analogues

General description

3,5-Di-tert-butyl-2-hydroxybenzaldehyde undergoes condensation reaction with
• methyl-2-{N-(2′-aminoethane)}-amino-1-cyclopentenedithiocarboxylate to yield Schiff base ligand
• N,N-diethyl-2-methyl-1,4-phenylenediamine during the synthesis of copper(II) and cobalt(II) complexes of salicylaldimine

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Peer-Reviewed Papers
15

References

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