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140910 Aldrich

Bathocuproine

96%

Synonym: 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, BCP

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Properties

Related Categories Bathocuproine (BCP), Building Blocks, Chemical Synthesis, Electron Transport and Hole Blocking Materials, Heterocyclic Building Blocks,
InChI Key   STTGYIUESPWXOW-UHFFFAOYSA-N
assay   96%
mp   279-283 °C(lit.)
absorption   λmax 280 nm in methanol
Orbital energy   HOMO 7 eV 
  LUMO 3.5 eV 
OLED Device Performance   ITO/CuPc/NPD/TCTA/mCP:FIrpic (6%)/BCP/LiF/Al
• Color: blue
• Max. EQE: 4.2 %
  ITO/NPD/CBP:Ir(ppy)3/BCP/Alq3/Mg:Al
• Color: green
• Max. Luminance: 100000 Cd/m2
• Max. EQE: 8 %
• Turn-On Voltage: 4.3 V
  ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq3/LiF/Al
• Color: red
• Max. Luminance: 24529 Cd/m2
• Max. EQE: 17 %
• Turn-On Voltage: 2.7 V
  ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
• Color: green
• Max. Luminance: 207839 Cd/m2
• Max. EQE: 21.6 %
• Turn-On Voltage: 2.1 V

Description

Frequently Asked Questions

Frequently Asked Questions are available for this Product.

Packaging

1 g in glass bottle

500 mg in glass bottle

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Frequently Asked Questions

Which document(s) contains shelf-life or expiration date information for a given product?
If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis. These documents are located on the product detail page under Useful Links & Tools. Click on the following link to search for a Certificate of Analysis. Please click the following link to see the details on our Product Dating Information.
How do I get lot-specific information or a Certificate of Analysis?
A Certificate of Analysis is available by lot number and can be obtained through our Advanced Search Option: http://www.sigmaaldrich.com/catalog/AdvancedSearchPage.do
How do I find price and availability?
There are several ways to find pricing and availability for our products.  Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers. 
What solvents can be used to dissolve Product 140910, Bathocuproine?
This product can be dissolved in 5% pyridine to yield a dark yellow solution. It is also soluble in methanol (36 mg/100ml), isoamyl alcohol (18 mg/100 ml), dioxane (100 mg/ml), 95% ethanol (50 mg/ml) and nitrobenzene.
What is the maximum absorbance wavelength for Product 140910, Bathocuproine?
The λmax is at approximately 280 nm in methanol.
What are the possible applications for Product 140910, Bathocuproine?
It can be used for Cu(I) detection, range 0.1-10 ppm, as it is a Cu(I)-specific colorimetric reagent. It is also an organic electron transporting material. For some detailed information, please check out the link: http://www.sigmaaldrich.com/catalog/search/TablePage/19353440.
What is the Department of Transportation shipping information for this product?
Transportation information can be found in Section 14 of the product's (M)SDS. To access the shipping information for this material, use the link on the product detail page for the product, or search here. 
My question is not addressed here, how can I contact Technical Service for assistance?
Use the option to the right to "Ask a Question" by email of a Technical Service Scientist.
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Protocols & Articles
Peer-Reviewed Papers
15

References

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