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144657 Aldrich

Trifluoroacetamide

97%

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Properties

Related Categories Amides, Building Blocks, C2 to C7, Carbonyl Compounds, Chemical Synthesis,
assay   97%
bp   162.5 °C(lit.)
mp   65-70 °C(lit.)

Description

Packaging

25, 100 g in glass bottle

Application

Trifluoroacetamide was used as probe for determination of membrane potential and extra/intracellular volume of erythrocytes by fluorine-19 NMR studies1.

General description

Trifluoroacetamide is a good quencher of tryptophan fluorescence2.

Price and Availability

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Safety & Documentation

Safety Information

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GHS07  GHS07
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Warning
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WGK Germany 
3

Protocols & Articles

Peer-Reviewed Papers

References

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1. Determination of membrane potential and cell volume by 19F NMR using trifluoroacetate and trifluoroacetamide probes. London RE and Gabel SA Biochemistry 28(6), 2378-82, (1989)

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2. Fluorescence quenching of tryptophan by trifluoroacetamide. Midoux P, Wahl P, Auchet JC, et al. Biochim. Biophys. Acta 801(1), 16-25, (1984)

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Determination of chloride potential in perfused rat hearts by nuclear magnetic resonance spectroscopy. Ramasamy R, Zhao P, Gitomer WL, et al. Am. J. Physiol. 263(6 Pt 2), H1958-62, (1992)

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Selective cross-coupling of organic halides with allylic acetates. Anka-Lufford LL, Prinsell MR, and Weix DJ J. Org. Chem. 77(22), 9989-10000, (2012)

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Photochemical functionalization of gallium nitride thin films with molecular and biomolecular layers. Kim H, Colavita PE, Metz KM, et al. Langmuir 22(19), 8121-6, (2006)

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Dual activation in asymmetric allylsilane addition to chiral N-acylhydrazones: method development, mechanistic studies, and elaboration of homoallylic amine adducts. Friestad GK, Korapala CS, and Ding H J. Org. Chem. 71(1), 281-9, (2006)

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An efficient synthesis of GDP-hexanolamine, a key tool for the purification of fucosyltransferases. Vincent SP and Gastinel LN Carbohydr. Res. 337(11), 1039-42, (2002)

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cis-Jasmone induces accumulation of defence compounds in wheat, Triticum aestivum. Moraes MC, Birkett MA, Gordon-Weeks R, et al. Phytochemistry 69(1), 9-17, (2008)

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Electrochemistry in deep eutectic solvents. Nkuku CA and LeSuer RJ J. Phys. Chem. B 111(46), 13271-7, (2007)

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Comparison of derivatives for determination of codeine and morphine by gas chromatography/mass spectrometry. Chen BH, Taylor EH, and Pappas AA J. Anal. Toxicol. 14(1), 12-7, (1990)

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Bulk magnetic susceptibility induced broadening in the 19F NMR of suspended leukemic cells. Adebodun F and Post JF NMR Biomed. 6(2), 125-9, (1993)

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Synthesis of carbazoles via an intramolecular cyclization of 2-(6-substituted 3(Z)-hexen-1,5-diynyl)anilines and their related molecules. Lee CY, Lin CF, Lee JL, et al. J. Org. Chem. 69(6), 2106-10, (2004)

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Peroxynitrite modification of protein thiols: oxidation, nitrosylation, and S-glutathiolation of functionally important cysteine residue(s) in the sarcoplasmic reticulum Ca-ATPase. Viner RI, Williams TD, and Schöneich C Biochemistry 38(38), 12408-15, (1999)

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Detection of cysteine conjugate metabolite adduct formation with specific mitochondrial proteins using antibodies raised against halothane metabolite adducts. Hayden PJ, Ichimura T, McCann DJ, et al. J. Biol. Chem. 266(28), 18415-8, (1991)

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Aryl C-glycosylation of phenols with glycosyl trifluoroacetimidates. Li Y, Wei G, and Yu B Carbohydr. Res. 341(16), 2717-22, (2006)

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First O-glycosylation of hydroxamic acids. Thomas M, Gesson JP, and Papot S J. Org. Chem. 72(11), 4262-4, (2007)

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Development of a diversity-oriented approach to oxazole-5-amide libraries. Thompson MJ, Adams H, and Chen B J. Org. Chem. 74(10), 3856-65, (2009)

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SAR study of 2,3,4,14b-tetrahydro-1H-dibenzo[b,f]pyrido[1,2-d][1,4]oxazepines as progesterone receptor agonists. Dols PP, Folmer BJ, Hamersma H, et al. Bioorg. Med. Chem. Lett. 18(4), 1461-7, (2008)

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The behaviour of deoxyhexose trihaloacetimidates in selected glycosylations. Comegna D, Bedini E, Di Nola A, et al. Carbohydr. Res. 342(8), 1021-9, (2007)

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Analysis of sibutramine metabolites as N-trifluoroacetamide and O-trimethylsilyl derivatives by gas chromatography-mass spectrometry in urine. Sardela VF, Motta MT, Padilha MC, et al. J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 877(27), 3003-11, (2009)

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Measurement of the diffusion of 2,2,2-trifluoroacetamide within thermoresponsive hydrogels using NMR imaging. Dinarvand R, Wood B, and D'Emanuele A Pharm. Res. 12(9), 1376-9, (1995)

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Modulation of the antioxidant activity of HO* scavengers by albumin binding: a 19F-NMR study. Aime S, Digilio G, Bruno E, et al. Biochem. Biophys. Res. Commun. 307(4), 962-6, (2003)

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1H-nuclear magnetic resonance spectroscopy of reducing-residue anomeric protons of pertrifluoroacetylated carbohydrates. Summerfelt ST, Selosse EJ, Reilly PJ, et al. Carbohydr. Res. 203(2), 163-72, (1990)

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Synthesis of fructofuranosides: efficient glycosylation with N-phenyltrifluoroacetimidate as the leaving group. Lian G, Gao Q, and Lin F Carbohydr. Res. 343(17), 2992-6, (2008)

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Design, synthesis and antibacterial activity of minor groove binders: the role of non-cationic tail groups. Khalaf AI, Bourdin C, Breen D, et al. Eur. J. Med. Chem. 56, 39-47, (2012)

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Enols as potent antibacterial agents. Thorarensen A, Zurenko GE, Sweeney MT, et al. Bioorg. Med. Chem. Lett. 11(22), 2931-4, (2001)

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Beil. 2,IV,471

Aldrich MSDS 1, 1755:D / Corp MSDS 1 (2), 3438:B / FT-IR 2 (1), 1260:A / FT-IR 1 (1), 752:B / FT-NMR 1 (1), 1223:B / IR-Spectra (2), 389:E / IR-Spectra (3), 439:G / RegBook 1 (1), 879:F / Structure Index 1, 134:D:5 / Vapor Phase 3, 778:C

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