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  • 14556 - (1S,9S)-1,9-Bis[(tert-butyldimethylsiloxy)methyl]-5-cyanosemicorrin

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14556 Aldrich

(1S,9S)-1,9-Bis[(tert-butyldimethylsiloxy)methyl]-5-cyanosemicorrin

≥97.0%

Synonym: Semicorrin chiral ligand 2

  • CAS Number 105251-52-3

  • Empirical Formula (Hill Notation) C24H45N3O2Si2

  • Molecular Weight 463.80

  •  Beilstein Registry Number 5153664

  •  MDL number MFCD00142698

  •  PubChem Substance ID 57647178

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Properties

Related Categories Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
InChI Key   JYNLYWZVXIGLJC-GLHDQHDCSA-N
assay   ≥97.0%
optical activity   [α]20/D −63±2°, c = 1% in chloroform
mp   74-77 °C
storage temp.   2-8°C

Description

Other Notes

The Cu(II) and Co(II) complexes are catalysts for enantioselective cyclopropanation and reduction reactions

Packaging

10 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Price and Availability

Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.



Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles

Articles

BOX

C2-symmetric chiral bisoxazolines (BOX) are privileged structures because they promote a great number of transformations with unprecedented selectivity.1 In 1991, in the same Journal of American Chem...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 64.
Keywords: Addition reactions, Asymmetric synthesis, Catalysis, Chemfiles, Cyclopropanations, Ligands, transformation

Peer-Reviewed Papers
15

References

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