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149497 Aldrich

Methyl diphenylphosphinite

97%

Synonym: Diphenylmethoxyphosphine, Methoxydiphenylphosphine, NSC 171167

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
InChI Key   OAADXJFIBNEPLY-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.604(lit.)
bp   149 °C/6 mmHg(lit.)
density   1.078 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

5 g in glass bottle

Application

Ased as:
• Catalyst for hydroformylative desymmetrization of bisalkenyl carbinols and bishomoallylic carbinols
• Ligand in rhodium-catalyzed hydroformylation of bishomoallylic alcohols
• Calatyst in preparation of γ-lactones via branched-regioselective hydroformylation reactions
• Ligand for nickel-catalyzed hydrocyanation reactions
• Catalyst in annulation reactions

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 2810 6.1 / PGIII
WGK Germany 
3
Flash Point(F) 
>235.4 °F
Flash Point(C) 
>113 °C
Protocols & Articles
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