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15217 Aldrich

Bis(trichloromethyl) carbonate

purum, ≥99.0% (AT)

Synonym: Triphosgene, tri-Phosgene

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Properties

Related Categories Building Blocks, Carbonates, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks More...
InChI Key   UCPYLLCMEDAXFR-UHFFFAOYSA-N
grade   purum
assay   ≥99.0% (AT)
mp   75-80 °C
storage temp.   2-8°C

Description

Other Notes

Crystalline, easy-to-handle substitute for phosgene; 1 mole of the reagent corresponds in its reactivity to 3 moles phosgene

Application

Bis(trichloromethyl) carbonate was used in the preparation of Fmoc-amino acid chlorides. It was also used in the preparation of aryl-(Z)-vinyl chlorides.

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2928 8(6.1) / PGII
WGK Germany 
2
Protocols & Articles
Peer-Reviewed Papers
15

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