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156841 Aldrich

(+)-Diethyl L-tartrate

≥99%

Synonym: L-(+)-Tartaric acid diethyl ester

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Epoxidation,
assay   ≥99%
optical activity   [α]20/D +8.5°, neat
optical purity   ee: ≥99% (GLC)
refractive index   n20/D 1.446(lit.)
bp   280 °C(lit.)
density   1.204 g/mL at 25 °C(lit.)

Description

General description

Made from natural tartaric acid

Packaging

25, 100, 500 g in glass bottle

Price and Availability

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Safety & Documentation

Safety Information

WGK Germany 
3
Flash Point(F) 
199.4 °F
Flash Point(C) 
93 °C

Protocols & Articles

Peer-Reviewed Papers

References

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Bioplastics from feather quill. Ullah A, Vasanthan T, Bressler D, et al. Biomacromolecules 12(10), 3826-32, (2011)

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Separation of corticosteroids by microemulsion EKC with diethyl L-tartrate as the oil phase. Wu CH, Chen TH, Huang KP, et al. Electrophoresis 28(20), 3691-6, (2007)

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A practical and azide-free synthetic approach to oseltamivir from diethyl D-tartrate. Weng J, Li YB, Wang RB, et al. J. Org. Chem. 75(9), 3125-8, (2010)

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Two-chiral component microemulsion EKC - chiral surfactant and chiral oil. Part 2: diethyl tartrate. Kahle KA and Foley JP Electrophoresis 28(15), 2644-57, (2007)

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Total synthesis of broussonetine F: the orthoamide Overman rearrangement of an allylic diol. Hama N, Aoki T, Miwa S, et al. Org. Lett. 13(4), 616-9, (2011)

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Influence of microemulsion chirality on chromatographic figures of merit in EKC: results with novel three-chiral-component microemulsions and comparison with one- and two-chiral-component microemulsions. Kahle KA and Foley JP Electrophoresis 28(17), 3024-40, (2007)

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Total syntheses of naturally occurring diacetylenic spiroacetal enol ethers. Miyakoshi N, Aburano D, and Mukai C J. Org. Chem. 70(15), 6045-52, (2005)

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Total synthesis of the light-harvesting carotenoid peridinin. Olpp T and Brückner R Angew. Chem. Int. Ed. Engl. 45(24), 4023-7, (2006)

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Pseudo-first-order alkaline hydrolysis of diethyl tartrate: a baseline study for a polymer matrix used in controlled-release delivery systems. Kalonia DS and Simonelli AP J. Pharm. Sci. 79(4), 364-8, (1990)

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Merck 14,3855

Beil. 3,IV,1232

Fieser 11,181

Aldrich MSDS 1, 682:D / Arctander, 916 / Corp MSDS 1 (1), 1227:A / FT-IR 1 (1), 663:C / FT-IR 2 (1), 1086:C / FT-NMR 1 (1), 1042:A / Fenaroli / IR-Spectra (2), 345:C / IR-Spectra (3), 389:D / NMR-Reference 2 (1), 559:A / RegBook 16 (1), 751:O / RegBook 1 (1), 751:O / Sigma FT-IR 1 (2), 900:A / Structure Index 1, 116:A:5 / Vapor Phase 3, 718:C

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