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163511 Aldrich

Hydroxymethanesulfinic acid monosodium salt dihydrate

Synonym: Sodium formaldehydesulfoxylate

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Properties

Related Categories Building Blocks, Chemical Synthesis, Free Radical Initiators, Inorganic Peroxides, Materials Science,
mp   64-68 °C(lit.)
solubility   alcohol: slightly soluble(lit.)
  benzene: slightly soluble(lit.)
  chloroform: slightly soluble(lit.)
  diethyl ether: slightly soluble(lit.)
  water: freely soluble(lit.)

Description

Packaging

1 kg in poly bottle

100 g in poly bottle

General description

Oxidation reation of hydroxymethanesulfinic acid with chlorite has been studied in the pH range 4-81. It is a sulfur-containing reducing agent2.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS08  GHS08
Signal word 
Warning
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Contact with acids liberates toxic gas.
Personal Protective Equipment 
Hazard Codes (Europe) 
Xn
Risk Statements (Europe) 
Safety Statements (Europe) 
36/37
WGK Germany 
1
RTECS 
PB0390000

Protocols & Articles

Peer-Reviewed Papers

References

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1. Oxyhalogen-Sulfur Chemistry: Oxidation of Hydroxymethanesulfinic Acid by Chlorite 1. Salem MA, et al. J. Phys. Chem. 100(22), 9377-84, (1996)

2. Recent trends in the chemistry of sulfur-containing reducing agents. Makarov, SV. Russ. Chem. Rev. 70(10), 885-95, (2001)

Reactive oxygen species in the aerobic decomposition of sodium hydroxymethanesulfinate. Makarov SV, Mundoma C, Svarovsky SA, et al. Arch. Biochem. Biophys. 367(2), 289-96, (1999)

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Merck 14,8620

Beil. 1,IV,3052

FT-NMR 1 (1), 1425:B / RegBook 1 (1), 1049:A / Structure Index 1, 162:D:8

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