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163511 Aldrich

Hydroxymethanesulfinic acid monosodium salt dihydrate

Synonym: Sodium formaldehydesulfoxylate

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Properties

Related Categories Building Blocks, Chemical Synthesis, Free Radical Initiators, Inorganic Peroxides, Materials Science,
mp   64-68 °C(lit.)
solubility   alcohol: slightly soluble(lit.)
  benzene: slightly soluble(lit.)
  chloroform: slightly soluble(lit.)
  diethyl ether: slightly soluble(lit.)
  water: freely soluble(lit.)

Description

Packaging

1 kg in poly bottle

100 g in poly bottle

General description

Oxidation reation of hydroxymethanesulfinic acid with chlorite has been studied in the pH range 4-81. It is a sulfur-containing reducing agent2.

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Safety & Documentation

Safety Information

Symbol 
GHS08  GHS08
Signal word 
Warning
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Contact with acids liberates toxic gas.
Personal Protective Equipment 
WGK Germany 
1
RTECS 
PB0390000

Protocols & Articles

Peer-Reviewed Papers

References

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1. Oxyhalogen-Sulfur Chemistry: Oxidation of Hydroxymethanesulfinic Acid by Chlorite 1. Salem MA, et al. J. Phys. Chem. 100(22), 9377-84, (1996)

2. Recent trends in the chemistry of sulfur-containing reducing agents. Makarov, SV. Russ. Chem. Rev. 70(10), 885-95, (2001)

Reactive oxygen species in the aerobic decomposition of sodium hydroxymethanesulfinate. Makarov SV, Mundoma C, Svarovsky SA, et al. Arch. Biochem. Biophys. 367(2), 289-96, (1999)

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Merck 14,8620

Beil. 1,IV,3052

FT-NMR 1 (1), 1425:B / RegBook 1 (1), 1049:A / Structure Index 1, 162:D:8

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