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163872 Aldrich

Ethyl malonyl chloride

technical grade

Synonym: Ethyl (chloroformyl)acetate, Ethyl 3-chloro-3-oxopropionate

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Properties

Related Categories Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks More...
grade   technical grade
InChI Key   KWFADUNOPOSMIJ-UHFFFAOYSA-N
refractive index   n20/D 1.429(lit.)
bp   79-80 °C/25 mmHg(lit.)
density   1.176 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

5, 25 g in glass bottle

Application

Ethyl malonyl chloride was used in the synthesis of:
• liquid-crystalline methanofullerodendrimers
• 3,5-disubstituted 1,2,4-oxadiazole derivatives, which are potential peptidomimetic building blocks
• 3-pyrrolin-2-ones via amidation with propargylamines and subsequent base catalyzed 5-exo-dig cyclization

General description

Ethyl malonyl chloride is a versatile acylating agent for propargyl alcohols, hydrazines and amines.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 3265 8 / PGIII
WGK Germany 
3
Flash Point(F) 
147.2 °F
Flash Point(C) 
64 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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