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164011 Aldrich

Methyl 3-chloro-3-oxopropionate

97%

Synonym: Methyl chloroformylacetate, Methyl malonyl chloride

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Properties

Related Categories Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks More...
InChI Key   UTBCRHAMJFMIIR-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.432(lit.)
bp   57-59 °C/12 mmHg(lit.)
density   1.273 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

5, 25 g in glass bottle

Application

Methyl 3-chloro-3-oxopropionate was used as a reagent in the synthesis of resin-bound 4-tosyl quinolinone, 1-anthracen-9-ylmethyl 3-methyl 2,2-dimethylmalonate and 1-(4-(3,5-dihydropyren-1-yl)butyl)-3-methyl 2,2-dimethylmalonate.

General description

Methyl 3-chloro-3-oxopropionate reacts with 4-cyano-1,1′-biphenyl derivatives bearing ω-hydroxyalkyl substituents to yield liquid-crystalline linear malonates and cyanoacetates.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3265 8 / PGII
WGK Germany 
3
Flash Point(F) 
176 °F
Flash Point(C) 
80 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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