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165336 Aldrich

Methylboronic acid

97%

Synonym: Methaneboronic acid

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Properties

Related Categories Alkyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents More...
InChI Key   KTMKRRPZPWUYKK-UHFFFAOYSA-N
assay   97%
mp   91-94 °C(lit.)

Description

Packaging

1, 5 g in glass bottle

Application

Reagent used for
• Palladium-catalyzed Stille and Suzuki-Miyaura cross-couplings
• Microwave-heated heterogeneous Palladium (Pd)-catalytized reactions
• Ruthenium (Ru)-catalyzed silylation reactions
• Bis(aminotropone) Titanium (Ti) catalysts for ethylene polymerizations
• Enantioselective asymmetric bromoaminocyclization and bromoaminocyclization using amino-thiocarbamate catalysts

Reagent used in Preparation of
• Common building blocks for pharmaceuticals and agrochemicals
• Chrysin analogs by Suzuki-Miyaura coupling reactions
• Casein kinase I inhibitors
• Divergent C-H functionalizations directed by sulfonamide pharmacophores in drug discovery

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Boronic Acids

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
Aldrich ChemFiles 2007, 7.7, 3.
Keywords: Chemfiles, Coupling reactions, Dehydration reaction, Suzuki coupling

Peer-Reviewed Papers
15

References

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