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17455 Aldrich

tert-Butyl α-bromoisobutyrate

≥98.0%

Synonym: tert-Butyl 2-bromo-2-methylpropionate

  • CAS Number 23877-12-5

  • Linear Formula (CH3)2CBrCOOC(CH3)3

  • Molecular Weight 223.11

  •  Beilstein Registry Number 1905654

  •  EC Number 245-924-7

  •  MDL number MFCD00051908

  •  PubChem Substance ID 24850484

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Properties

Related Categories ATRP, ATRP Initiators, Building Blocks, C8 to C9, Carbonyl Compounds,
InChI Key   IGVNJALYNQVQIT-UHFFFAOYSA-N
assay   ≥98.0%
refractive index   n20/D 1.436
density   1.196 g/mL at 20 °C(lit.)

Description

Packaging

100, 500 mL in glass bottle

Application

tert-Butyl α-bromoisobutyrate was used as an initiator in the atom transfer radical polymerisation (ATRP) of 2-(acetoacetoxy)ethyl methacrylate (AEMA).

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
2

Documents

Certificate of Analysis

Protocols & Articles

Articles

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

In 2006, Matyjaszewski and co-workers first described controlled radical polymerization by Activators ReGenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP),1-3 a developm...
Keywords: Antimicrobials, Ligands, Nanotubes, Oxidations, Polymerization reactions, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization, Solvents

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

Emergence of living radical polymerization mediated by transition metal catalysts in 1995 was a seminal piece of work in the field of synthetic polymer chemistry.1-3 Since this date, many transition ...
Keywords: Catalysis, Condensations, Evaporation, Filtration, Ligands, Oxidations, Polymer science, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Solvents

Typical Procedures for Polymerizing via ATRP

The following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.
Keywords: Gas chromatography, Ligands, Nuclear magnetic resonance spectroscopy, Polymerization reactions, Size-exclusion chromatography, Solvents

Peer-Reviewed Papers
15

References

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