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174653 Aldrich

Triethyl 2-phosphonopropionate

98%

Synonym: 2-(Diethoxyphosphoryl)propionic acid ethyl ester

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents More...
InChI Key   BVSRWCMAJISCTD-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.431(lit.)
bp   143-144 °C/12 mmHg(lit.)
density   1.111 g/mL at 25 °C(lit.)

Description

Packaging

10, 50 g in glass bottle

Application

Reactant involved in:
• Intramolecular conjugate addition for the synthesis of floresolide B
• Chemoenzymatic one-pot synthesis of γ-butyrolactones
• Enantioselective synthesis of spiroindane di-Me acetic acid via asymmetric hydrogenation
• Stereoselective intramolecular Diels-Alder reactions
• Horner-Wadsworth-Emmons reactions

This Wittig-Horner reagent condenses with a wide variety of aldehydes and ketones to form acrylates.

Price and Availability


Cross-Coupling Guide
Safety & Documentation
Protocols & Articles
Peer-Reviewed Papers
15

References

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