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176494 Aldrich

Europium tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]

Synonym: Eu(facam)3, Eu(tfc)3, Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate], Tris(3-trifluoroacetyl-d-camphorato)europium(III), Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Resolution Reagents, Chiral Shift Reagents, NMR - Buffers and Reagents,
InChI Key   BWIHMSGCCRUUCZ-NCJHBDPTSA-K
optical activity   [α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)

Description

Application

Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride.

Reactant involved in:
• The synthesis of europium acetylcamphorate phosphine oxide complexes
• Reactions with 1,10-N,N′-phenanthroline dioxide derivatives

Packaging

1 g in glass bottle

100 mg in glass bottle

Price and Availability


Stable Isotope
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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