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177261 Aldrich

DPPF Green Alternative

97%

Synonym: 1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf

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Properties

Related Categories 12 Principles Aligned Products, Related Palladacycles, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry,
InChI Key   HPXNTHKXCYMIJL-UHFFFAOYSA-N
assay   97%
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   181-182 °C (dec.)(lit.)
ligand for   Buchwald-Hartwig Cross Coupling Reaction
  Carbonylations
  Ene Reaction
  Heck Reaction
  Negishi Coupling
  Sonogashira Coupling
  Stille Coupling
  Suzuki-Miyaura Coupling
  Tsuji-Trost Reaction

Description

Packaging

1, 10, 25, 250 g in glass bottle

Application

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Development of Pd/C-Catalyzed Cyanation of Aryl Halides

An orthogonal set of catalyst systems has been developed for the Suzuki?Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for t...

Peer-Reviewed Papers
15

References

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