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178713 Aldrich

9-Borabicyclo[3.3.1]nonane dimer

Synonym: 9-BBN

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   IYDIZBOKVLHCQZ-GEEKYZPCSA-N
mp   150-152 °C(lit.)

Description

Application

Air-stable, crystalline reagent used to reductively cleave cyclic acetals and ketals to monobenzylated 1,2-diols.

Employed in the hydroboration of alkynes, nitriles, and ketones.

Reagent found to reduce peroxo esters to alcohols without concomitant reduction of the peroxo linkage.

Packaging

5, 25, 100 g in glass bottle

Price and Availability


Laboratory Gloves

Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 3396 4.1(4.3) / PGII
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Reagents for C–C Bond Formation

Aldrich carries a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations

Peer-Reviewed Papers
15

References

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