Synonym: Iodobenzene I,I-diacetate, Iodosobenzene I,I-diacetate
|Related Categories||C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis, Hypervalent Iodine, Oxidants,|
Stoichiometric oxidant in the TEMPO oxidation of nerol to neral.1 Oxidant employed in the rhodium-catalyzed aziridination of olefins with sulfamate esters.2
Unactivated sp3 C-H bonds of both oxime and pyridine substrates undergo highly regio- and chemoselective Pd(II)-catalyzed oxygenation with PhI(OAc)2 as a stoichiometric oxidant.
Used in the room temperature Pd-catalyzed 2-arylation of indoles
Useful reagent for the synthesis of a wide variety of heterocyclic compounds.
1 kg in glass bottle
5, 25, 100 g in glass bottle
Certificate of Analysis
Certificate of Origin
The allenylboronate platform has recently been demonstrated to undergo multicomponent reactions in a completely regio- and stereoselective fashion.1 Yoshida and co-workers successfully utilized this ...
Aldrich ChemFiles 2007, 7.1, 6.
Keywords: Anti-depressants, Anti-inflammatory agents, Building blocks
By substituting tetramethylated m-benzenediproprionic acid 1 via a decarboxylative metathesis of Rh2(OAc)4 (Scheme 9), the Du Bois group at Stanford has improved the catalytic performance of Rh with ...
ChemFiles Volume 5 Article 10
Keywords: Aminations, Asymmetric synthesis, Catalysis, Cyclizations, Metathesis, Poisons, Solvents
By substituting tetramethylated m-benzenediproprionic acid 1 via a decarboxylative metathesis of Rh2(OAc)4 (Scheme 1), the Du Bois group at Stanford has improved the catalytic performance of Rh with ...
Keywords: Aminations, Asymmetric synthesis, Catalysis, Cyclizations, Metathesis, Methods, Poisons, Solvents
1. Organic Synth. 83, 18, (2006)
2. Tetrahedron 62, 11331, (2006)
Synlett, 221, (1994)
Aldrichimica Acta 27, 15, (1994)
A one-pot oxidative decarboxylation-Friedel-Crafts reaction of acyclic alpha-amino acid derivatives activated by the combination of iodobenzene diacetate/iodine and iron dust. Fan R, Li W, and Wang B Org. Biomol. Chem. 6(24), 4615-21, (2008)
Structural studies on bioactive compounds. 32. Oxidation of tyrphostin protein tyrosine kinase inhibitors with hypervalent iodine reagents. Wells G, Seaton A, and Stevens MF J. Med. Chem. 43(8), 1550-62, (2000)
Fieser 1,508 / Fieser 3,166 / Fieser 4,266 / Fieser 10,214 / Fieser 12,384 / Fieser 15,258 / Fieser 16,275 / Fieser 17,280
FT-IR 2 (2), 2780:A / FT-IR 1 (2), 272:A / IR-Spectra (2), 887:E / IR-Spectra (3), 1013:D / RegBook 1 (2), 1863:F / Sax 6, 1622 / Structure Index 1, 179:E:1
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