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178934 Aldrich

Boron trichloride solution

1.0 M in methylene chloride

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Properties

Related Categories 25mL Sure/Seal Reagents, Acids, Acids & Bases, Boron, Catalysis and Inorganic Chemistry,
vapor pressure   29.72 psi ( 55 °C)
  9.05 psi ( 20 °C)
InChI Key   FAQYAMRNWDIXMY-UHFFFAOYSA-N
concentration   1.0 M in methylene chloride
density   1.326 g/mL at 25 °C
storage temp.   2-8°C

Description

Application

For preparing methyl esters of fatty acids and for transesterification of triglycerides.

Boron trichloride may be used in the synthesis of Cl-BODIPYs (BODIPY - Boron-dipyrromethene) and tris(dimethylamino)borane. It may be used in the synthesis of sceptrins and nakamuric acid.

Packaging

2 L in Sure/Seal™

4×25, 100, 800 mL in Sure/Seal™

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

General description

Boron trichloride is a boron halide. It participates in the hydroboration of alkenes. It forms strongly polarized donor-acceptor complexes with trimethyl- and triethylsilyl triflate. Boron trichloride assisted reaction between acid chlorides and alkynyltrifluoroborate salts have been reported to form ynones.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Target organs 
Blood, Central nervous system, Liver
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 2922 6.1(8) / PGII
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Acids and Bases

Acids and bases have been used by chemists for centuries, and are among the most fundamental reagents employed in synthetic organic chemistry. This Aldrich product line ranges from Brønsted and Lewis...
Chemfiles Volume 1 Article 3

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Peer-Reviewed Papers
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