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179043 Aldrich

Borane N,N-diethylaniline complex

Synonym: (N,N-Diethylaniline)trihydroboron, Diethylphenylamine-borane, NSC 239123

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   YPWBYWNNJVSNPQ-UHFFFAOYSA-N
mp   −30-−27 °C(lit.)
density   0.917 g/mL at 25 °C(lit.)

Description

Packaging

25, 100 g in Sure/Seal™

Application

Reactant for:
• Diastereoselective reduction of prochiral enone intermediates
• Borylation of aryl halides
• Reductions of ketones, acids, esters, amides, and nitriles
• Investigations of borane source on enantioselectivity in enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones

Reactant for synthesis of:
• Chromanol derivatives as CETP inhibitors for the treatment of cardiovascular disease
• Allylic alcohols via enantioselective reductions
• Pinacolboranes for one-pot synthesis of unsymmetrical biaryls

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN3398 - DOT UN3399 class 4.3 - PG 2 - Organometallic substance, liquid, water-reactive, HI: all (not BR)
WGK Germany 
3
Flash Point(F) 
69.8 °F
Flash Point(C) 
21 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
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